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Merck

243663

Sigma-Aldrich

次亚磷酸钠 水合物

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About This Item

线性分子式:
NaH2PO2 · xH2O
分子量:
87.98 (anhydrous basis)
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.55
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方案

~95% (NaH2PO2)

表单

powder, crystals or chunks

SMILES字符串

O.[Na+].OP[O-]

InChI

1S/Na.H3O2P.H2O/c;1-3-2;/h;3H2,(H,1,2);1H2/q+1;;/p-1

InChI key

PLZNPHDJGFDNRM-UHFFFAOYSA-M

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相关类别

应用

Sodium hypophosphite hydrate can be used as:
  • A radical precursor to synthesize mono alkyl phosphinic acids via radical reaction with alkenes in the presence of Et3B as the initiator.[1]
  • A reagent for the reduction of the diazonium salt.[2]
  • A hydrogen donor in the transfer-hydrogenation reactions.[3]
  • A catalyst in the esterification reaction.[4]

It can also be used to compose the finishing solutions for the immobilization of photo-initiator (benzophenone ) onto cotton fabrics.[5]
Sodium hypophosphite hydrate is widely used as an esterification catalyst.[6] It may be used to compose the finishing solutions for the incorporation of benzophenone (photoinitiator) onto cotton fabrics.[5][7]

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

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Effect of wood filler treatment and EBAGMA compatibilizer on morphology and mechanical properties of low density polyethylene/olive husk flour composites.
Kaci M, et al.
Express Polymer Letters, 1(7), 467-473 (2007)
Convenient synthesis of 4-methylhistamine and racemic. alpha., 4-dimethylhistamine and. alpha., 4-dimethylhistidine
Davey DD and Lumma Jr WC
The Journal of Organic Chemistry, 54(13), 3211-3213 (1989)
Chlorination of aniline and methyl carbanilate by N-chlorosuccinimide and synthesis of 1, 3, 5-trichlorobenzene
Davis Matthew C
Synthetic Communications, 39(6), 1100-1108 (2009)
Photoactive antibacterial cotton fabrics treated by 3, 3', 4, 4'-benzophenonetetracarboxylic dianhydride.
Hong KH and Sun G.
Carbohydrate Polymers, 84(3), 1027-1032 (2011)
S Deprèle et al.
The Journal of organic chemistry, 66(20), 6745-6755 (2001-10-02)
A novel and practical approach to monosubstituted phosphinic acid (alkylphosphonous acid) derivatives from hypophosphite salts or esters is described. Phosphorus-centered radical formation is initiated with Et(3)B/O(2), and the reaction is conveniently conducted at room temperature in an open flask. In

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