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Merck

212946

Sigma-Aldrich

氯化亚铜

reagent grade, 97%

别名:

一氯化铜

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预计发货时间2025年4月21日详情


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25 G
$118.00
500 G
$173.00
2 KG
$323.00

About This Item

线性分子式:
CuCl
CAS号:
分子量:
99.00
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.55

$118.00


预计发货时间2025年4月21日详情


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等級

reagent grade

蒸汽壓力

1.3 mmHg ( 546 °C)

化驗

97%

形狀

powder

反應適用性

reagent type: catalyst
core: copper

pH值

5 (20 °C, 50 g/L)

bp

1490 °C (lit.)

mp

430 °C (lit.)

溶解度

dimethyl sulfide: partially soluble(lit.)
water: insoluble(lit.)

SMILES 字串

Cl[Cu]

InChI

1S/ClH.Cu/h1H;/q;+1/p-1

InChI 密鑰

OXBLHERUFWYNTN-UHFFFAOYSA-M

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一般說明

Cu 在 CuCl 中以 + 1(亚铜)价态存在。[1]CuCl 是一种具有宽带隙的半导体。由于其晶格与硅相似,因此是硅光电器件的一种很有前途的候选材料。参与格氏试剂的各种反应。[2]

應用

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
氯化铜 (I)(氯化亚铜,CuCl)已用于合成 7-((叔 -丁基二甲基硅基)氧)七-2,4-二炔-1-醇。[3]CuCl 可用于环共轭二烯的立体定向合成。[4]它可用作研究氯化铜络合物在水热溶液中稳定性的反应物。[1]

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Copper (I) chloride-mediated intramolecular coupling of vinyltrimethylstannane and vinyl halide functions.
Piers E and Wong T.
The Journal of Organic Chemistry, 58(14), 3609-3610 (1993)
Takayoshi Arai et al.
The Journal of organic chemistry, 73(13), 4903-4906 (2008-06-03)
A catalytic asymmetric Henry reaction has been developed with use of a sulfonyldiamine-CuCl complex as a catalyst. A series of new binaphthyl-containing sulfonyldiamine ligands (2a-h) were readily synthesized in two steps starting from commercially available chiral 1,2-diamines. The (R,R)-diamine-(R)-binaphthyl ligand
Xiaoliang Xu et al.
Organic letters, 12(5), 897-899 (2010-02-04)
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.
Experimental study of copper (I) chloride complexing in hydrothermal solutions at 40 to 300 ?C and saturated water vapor pressure.
Xiao Z, et al.
Geochimica et Cosmochimica Acta, 62(17), 2949-2964 (1998)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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