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Merck

254185

Sigma-Aldrich

溴化铜

99.999% trace metals basis

别名:

一溴化铜

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10 G
$324.00
100 G
$1,540.00

$324.00


预计发货时间2025年4月21日详情


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10 G
$324.00
100 G
$1,540.00

About This Item

线性分子式:
CuBr
CAS号:
分子量:
143.45
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

$324.00


预计发货时间2025年4月21日详情


获取大包装报价

质量水平

方案

99.999% trace metals basis

表单

powder

反应适用性

reagent type: catalyst
core: copper

杂质

≤15.0 ppm Trace Metal Analysis

mp

504 °C (lit.)

密度

4.71 g/mL at 25 °C (lit.)

应用

battery manufacturing

SMILES字符串

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1

InChI key

NKNDPYCGAZPOFS-UHFFFAOYSA-M

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一般描述

溴化亚铜(I)是一种淡绿色的无机抗磁性固体,具有像硫化锌一样的聚合结构。不溶于水,广泛应用于催化、纳米材料合成和太阳能电池等领域。

应用

溴化亚铜(I)可用于:
  • 作为有机太阳能电池(OSC)的溶液可加工空穴传输层(HTL)。CuBr可提高太阳能电池的能量转换效率。[1]
  • 作为合成光致发光金属有机框架(MOF)的前体。[2]
  • 合成高发光性三配位铜(I)配合物作为OLED的掺杂剂,其最大外部量子效率为21.3%。[3]
  • 与配体作为催化剂在14种不同溶剂中进行叔烷基卤化物的原子转移自由基聚合(ATRP)反应,测定速率常数。
  • 分子内自由基陷阱辅助原子转移自由基偶联法合成大环聚合物。

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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An acs-Type Metal--Organic Framework with an Unprecedented Undecanuclear Copper Cluster as Secondary Building Unit
Sheng Hu, et al.
European Journal of Inorganic Chemistry, 2012, 3669-3673 (2012)
Highly Efficient Green Organic Light-Emitting Diodes Containing Luminescent Three-Coordinate Copper(I) Complexes
Masashi Hashimoto, et al.
Journal of the American Chemical Society, 133, 10348-10351 (2011)
Carla Sardo et al.
International journal of pharmaceutics, 563, 347-357 (2019-04-03)
Sustained pulmonary delivery of tobramycin from microparticles composed of drug/polymer nanocomplexes offers several advantages against traditional delivery methods. Namely, in patients with cystic fibrosis, microparticle delivery can protect the tobramycin being delivered from strong mucoadhesive interactions, thus avoiding effects on
Copper Bromide as an Efficient Solution-Processable Hole Transport Layer for Organic Solar Cells: Effect of Solvents
Ranoo Bhargav, et al.
ACS Omega, 4, 6028-6034 (2019)
Thomas F Cooke et al.
Cell, 171(2), 427-439 (2017-10-07)
Parrot feathers contain red, orange, and yellow polyene pigments called psittacofulvins. Budgerigars are parrots that have been extensively bred for plumage traits during the last century, but the underlying genes are unknown. Here we use genome-wide association mapping and gene-expression

商品

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

相关内容

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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