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Merck

79266

Supelco

三甲基苯基氢氧化铵 溶液

~0.5 M (CH3)3N(OH)C6H5 in methanol, for GC derivatization, LiChropur

别名:

苯基三甲基氢氧化铵

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About This Item

线性分子式:
(CH3)3N(OH)C6H5
CAS号:
分子量:
153.22
Beilstein:
3917033
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NA.22

等级

derivatization grade ((GC derivatization))
for GC derivatization

质量水平

表单

liquid

质量

LiChropur

反应适用性

reagent type: derivatization reagent
reaction type: Esterifications

浓度

~0.5 M (CH3)3N(OH)C6H5 in methanol

技术

gas chromatography (GC): suitable

杂质

≤0.2% halides (as chloride)

储存温度

2-8°C

SMILES字符串

[OH-].C[N+](C)(C)c1ccccc1

InChI

1S/C9H14N.H2O/c1-10(2,3)9-7-5-4-6-8-9;/h4-8H,1-3H3;1H2/q+1;/p-1

InChI key

HADKRTWCOYPCPH-UHFFFAOYSA-M

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一般描述

Trimethylphenylammonium hydroxide (TMAH) is a methylating reagent.

应用

Learn more in the Product Information
Suitable for the derivatization of amino acids, n-methyl and n-aryl carbamates and fatty acids, clonidine, and substituted phenylureas.
TMAH may be used as a 0.1 mole/litre solution in methanol to determine plasma concentrations of carbamazepine and other anticonvulsant drugs, including phenobarbital, diphenylhydantoin, primidone, and mephenytoin using Gas-Liquid Chromatography.

其他说明

Reagent for n-methyl and methyl esters.

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

免责声明

Sales restrictions may apply

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 1

靶器官

Eyes

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

51.8 °F - closed cup

闪点(°C)

11 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Simultaneous determination of carbamazapine ("Tegretol") and other anticonvulsants in human plasma by gas-liquid chromatography.
J C Roger et al.
Clinical chemistry, 19(6), 590-592 (1973-06-01)
A Ranz et al.
Journal of biochemical and biophysical methods, 69(1-2), 3-14 (2006-03-28)
In the present study, a derivatization method for the determination of acidic herbicides has been investigated. This procedure involves the methylation with the quaternary ammonium salt trimethylanilinium hydroxide (TMAH) directly in the gas chromatographic auto-sampler vial for analysis by gas
Timothy J Jensen et al.
Journal of photochemistry and photobiology. B, Biology, 100(2), 100-111 (2010-06-19)
Five cationic porphyrins bearing one to four -N(CH(3))(3)(+) groups linked to the p-phenyl positions of 5,10,15,20-tetraphenylporphyrin (TPP) were synthesized in order to study the effect of overall charge and its distribution on the cellular uptake, phototoxicity and intracellular localization using
Alec N Salt et al.
Hearing research, 283(1-2), 14-23 (2011-12-20)
It has been widely believed that drug entry from the middle ear into perilymph occurs primarily via the round window (RW) membrane. Entry into scala vestibuli (SV) was thought to be dominated by local, inter-scala communication between scala tympani (ST)
R W Gullick et al.
Environmental science & technology, 35(7), 1523-1530 (2001-05-12)
A natural shale and four synthetic organoclays were compared as potential sorbent additives to containment barriers at hazardous waste sites. Trimethylphenyl ammonium bentonite (TMPA-bent) was shown in batch experiments to have the greatest sorption capacities for 1,2,4-trichlorobenzene, trichloroethylene, and methyl

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