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Merck
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文件

77460

Sigma-Aldrich

2-Chloroacetophenone

purum, ≥98.0% (GC)

别名:

ω-Chloroacetophenone, Phenacyl chloride

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About This Item

线性分子式:
C6H5COCH2Cl
CAS号:
532-27-4
分子量:
154.59
Beilstein:
507950
EC號碼:
208-531-1
MDL號碼:
MFCD00000933
分類程式碼代碼:
12352100
PubChem物質ID:
329767699
NACRES:
NA.22

等級

purum

品質等級

200

化驗

≥98.0% (GC)

形狀

crystals

bp

244-245 °C (lit.)

mp

53-56 °C
54-56 °C (lit.)

密度

1.324 g/mL at 25 °C (lit.)

SMILES 字串

ClCC(=O)c1ccccc1

InChI

1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

InChI 密鑰

IMACFCSSMIZSPP-UHFFFAOYSA-N

基因資訊

human ... PTPN6(5777)

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相关类别

一般說明

2-Chloroacetophenone is an organic building block used in the synthesis of heterocyclic compounds. It has low solubility in water but can be soluble in alcohols, ethers and other organic solvents.

應用

2-Chloroacetophenone can be used in the synthesis of phenyl acetic acid by Photo-Favorskii rearrangement. It is also used in the preparation of 1-(2-chlorophenyl)ethanol via asymmetric hydrogenation reaction.

訊號詞

Danger

危險分類

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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分析证书(COA)

Lot/Batch Number
0000375888
0000372760
0000375888
0000372760
0000213683

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Preparation of microgel-supported chiral catalysts and their application in the asymmetric hydrogenation of aromatic ketones
Deng J, et al.
Reactive and Functional Polymers, 72, 378-382 (2012)
Experimental study of the adsorption of 2-Chloroacetophenone at the air-environmental water interface
Hao, et al.
Frontiers in environmental science., 10, 2254-2254 (2022)
Lenilson C Rocha et al.
Biotechnology letters, 31(10), 1559-1563 (2009-06-06)
The asymmetric reduction of 2-chloro-1-phenylethanone (1) by seven strains of marine fungi was evaluated and afforded (S)-(-)-2-chloro-1-phenylethanol with, in the best case, an enantiomeric excess of 50% and an isolated yield of 60%. The ability of marine fungi to catalyse
Anil K Nigam et al.
Journal of hazardous materials, 184(1-3), 506-514 (2010-09-17)
Pyrolysis-GC/MS system with on-line micro-furnace was used to make rapid evaluation of ω-chloroacetophenone (CN) decomposition under inert thermal atmospheres. The volatile products evolved during pyrolysis were analyzed by thermal gravimetric analysis (TGA) and Py-GC/MS to obtain specific thermogram and pyrogram.
Expanding the [1,2]-aryl migration to the synthesis of substituted indoles.
Tao Pei et al.
Angewandte Chemie (International ed. in English), 47(22), 4231-4233 (2008-04-30)
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