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Merck

152463

Sigma-Aldrich

2-甲基-2-丁醇

ReagentPlus®, 99%

别名:

tert-Amyl alcohol, 叔戊醇

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250 ML
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250 ML
$131.00
1 L
$239.00
2.5 L
$343.00
18 L
$1,830.00

About This Item

线性分子式:
CH3CH2C(CH3)2OH
CAS号:
分子量:
88.15
Beilstein:
1361351
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

$131.00


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等级

reagent

质量水平

蒸汽密度

3 (vs air)

蒸汽压

12 mmHg ( 20 °C)

产品线

ReagentPlus®

方案

99%

表单

liquid

自燃温度

819 °F

expl. lim.

9 %

dilution

(for general lab use)

折射率

n20/D 1.405 (lit.)

pH值(酸碱度)

6.0 (20 °C, 118 g/L)

沸点

102 °C (lit.)

mp

−12 °C (lit.)

密度

0.805 g/mL at 25 °C (lit.)

SMILES字符串

CCC(C)(C)O

InChI

1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3

InChI key

MSXVEPNJUHWQHW-UHFFFAOYSA-N

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一般描述

2-甲基-2-丁醇是戊醇的异构形式。2-甲基-2-丁醇的各种物理性质(静电介电常数、粘度、密度、超声波和介电弛豫)已经在很宽的温度范围内进行了评估。[1]其作为溶剂,从水溶液中萃取糠醛的能力已经得到了测试。[2]在不存在溶剂的情况下,由市售钯基催化剂催化的MBY与氢的三相反应的动力学参数也已有描述。[3]

应用

2-甲基-2-丁醇(-戊醇, t-AmylOH,MBY)已被用作溶解阿佛丁[2,2,2-三溴乙醇]的溶剂,[4] 阿佛丁可在免疫组织化学研究中用作麻醉剂。[5]它已被用于制备(E)-2-(2-(3-乙氧基-3-氧代丙-1-烯基)-6-氟苯基)乙酸。[6]

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Central nervous system, Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

68.9 °F - closed cup

闪点(°C)

20.5 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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General kinetic modeling of the selective hydrogenation of 2-methyl-3-butyn-2-ol over a commercial palladium-based catalyst.
Vernuccio S, et al.
Industrial & Engineering Chemistry Research, 54(46), 11543-11551 (2015)
Ternary and Binary LLE Measurements for Solvent (4-Methyl-2-pentanone and 2-Methyl-2-butanol)+ Furfural+ Water between 298 and 401K.
Ma?nnisto? M, et al.
Journal of Chemical and Engineering Data, 61(2), 903-911 (2016)
Molecular association and dynamics in n-pentanol and 2-methyl-2-butanol: Ultrasonic, dielectric and viscosity studies at various temperatures.
D'Aprano A, et al.
Molecular Physics, 55(2), 475-488 (1985)
Surya Pandey et al.
Nature protocols, 15(4), 1459-1483 (2020-02-23)
The immune system operates at the scale of the whole organism in mammals. We currently lack experimental approaches to systematically track and study organism-wide molecular processes in mice. Here we describe an integrated toolkit for measuring gene expression in whole
Changyong Tang et al.
STAR protocols, 2(1), 100374-100374 (2021-03-09)
Adult neurogenesis, a process of generating newborn neurons from adult neural stem cells, is required for brain homeostasis, cognition, and affective behaviors. Deciphering the molecular mechanisms underlying adult neurogenesis will provide valuable insights into the functional integrity of the adult

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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