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Merck

86262

Sigma-Aldrich

2-甲基-2-丁烯

≥95.0% (GC)

别名:

β-异戊烯, 戊烯

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50 ML
$72.90
250 ML
$164.00
1 L
$518.00

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国内现货,预计发货时间2025年4月11日详情


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50 ML
$72.90
250 ML
$164.00
1 L
$518.00

About This Item

线性分子式:
CH3CH=C(CH3)2
CAS号:
分子量:
70.13
Beilstein:
1361353
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$72.90


国内现货,预计发货时间2025年4月11日详情


获取大包装报价

蒸汽密度

2.4 (vs air)

方案

≥95.0% (GC)

表单

liquid

expl. lim.

8.7 %

折射率

n20/D 1.385 (lit.)
n20/D 1.388

沸点

35-38 °C (lit.)

mp

−134 °C (lit.)

密度

0.662 g/mL at 25 °C (lit.)

SMILES字符串

C\C=C(\C)C

InChI

1S/C5H10/c1-4-5(2)3/h4H,1-3H3

InChI key

BKOOMYPCSUNDGP-UHFFFAOYSA-N

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一般描述

2-甲基-2-丁烯是一种三取代烯烃。它可作为客体,与自组装二苯甲酮-尿素大环形成稳定的固态主客体络合物。[1]相关研究包括:活性氯对2-甲基-2-丁烯光氧化的影响。[2]2-甲基-2-丁烯吸附到Na-ZSM-5沸石内部骨架上可进行光敏氧化反应。[3]2-甲基-2-丁烯可与臭氧发生气相反应。[4]2-甲基-2-丁烯可与3-甲基噻吩在负载的磷酸上进行液相烷基化反应的动力学。[5]

[5]2-甲基-2-丁烯可通过紫外照射形成三亚甲基氧化物。[6]

应用

出于校准目的,2-甲基-2-丁烯可以用作过氧乙酰硝酸盐的前体。[4]

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 1 - Muta. 2 - STOT SE 3

靶器官

Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

-4.0 °F

闪点(°C)

-20 °C

个人防护装备

Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Kinetics and mechanism of liquid-phase alkylation of 3-methylthiophene with 2-methyl-2-butene over a solid phosphoric acid.
Belliere V, et al.
Applied Catalysis. B, Environmental, 64(3), 254-261 (2006)
Light-catalyzed organic reactions. I. The reaction of carbonyl compounds with 2-methyl-2-butene in the presence of ultraviolet light
Buchi G, et al.
Journal of the American Chemical Society, 76, 4327-4331 (1954)
Light-catalyzed organic reactions. I. The reaction of carbonyl compounds with 2-methyl-2-butene in the presence of ultraviolet light
Buchi G, et al.
Journal of the American Chemical Society, 76, 4327-4331 (1954)
Mehdi Nabi et al.
Journal of AOAC International, 103(5), 1243-1249 (2020-11-27)
A simple, rapid, selective and sensitive sample preparation and derivatization method was performed for determination of bromate ions in water by means of dispersive liquid-liquid extraction (DLLE) by gas chromatography-electron capture detection (GC-ECD). This method is based on 2-methyl-2-butene derivatization
Gas-phase reaction of ozone with 2-methyl-2-butene: Dicarbonyl formation from Criegee biradicals.
Grosjean D.
Environmental Science & Technology, 24(9), 1428-1432 (1990)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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