If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
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About This Item
推荐产品
品質等級
產品線
Novabiochem®
化驗
≥99.0% (GC)
形狀
powder
自燃溫度
420 °C
效力
140 mg/kg LD50, oral (Rat)
90 mg/kg LD50, skin (Rabbit)
反應適用性
reaction type: Coupling Reactions
製造商／商標名
Novabiochem®
pH值
11 (20 °C, 60 g/L in H2O)
bp
138-140 °C/24 hPa
mp
110-112 °C
轉變溫度
flash point 124 °C
體積密度
520 kg/m3
應用
peptide synthesis
儲存溫度
2-30°C
SMILES 字串
[N+](=C1C=CNC=C1)(C)C
InChI
1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3/p+1
InChI 密鑰
VHYFNPMBLIVWCW-UHFFFAOYSA-O
一般說明
参考文献
[1] S. S. Wang, et al. (1981) Int. J. Peptide Protein Res., 18, 459.
[2] J.-P. Gamet, et al. (1984) Tetrahedron, 40, 1995.
[3] K. Takeda, et al. (1991) Synthesis, 1991, 689.
應用
- 以DMAP为引发剂的β‐丁内酯共聚研究：本研究重点研究了DMAP在β‐丁内酯开环聚合中的应用，并分析了其作为催化剂的效率（Palenzuela et al., 2024）。
- 卤素键促进直接交叉偶联：本文详细介绍了DMAP在烷基溴与香豆素交叉偶联催化过程中的应用，强调了DMAP在光照下的作用（Guo et al., 2024）。
- 羧酸对映体特异性分析：讨论了DMAP在羧酸对映特异性分析中优于Et3N等其他催化剂的功效（Mo et al., 2024）。
聯結
分析報告
物质外观（目视检查）：粉末
鉴别(IR）：符合检验
溶解度（1 毫摩尔溶于2 ml DMF中）：明显可溶
含量测定（GC，面积%）： ≥ 99.0 %（a/a）
熔程（下限值）： ≥ 110 °C
熔程（上限值）： ≤ 113 °C
法律資訊
訊號詞
Danger
危險分類
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 1
標靶器官
Nervous system
儲存類別代碼
6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
255.2 °F
閃點（°C）
124 °C
其他客户在看
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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