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Merck

T24503

Sigma-Aldrich

四甲基脲

99%

别名:

1,1,3,3-四甲基脲, TMU

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About This Item

线性分子式:
(CH3)2NCON(CH3)2
CAS号:
分子量:
116.16
Beilstein:
773898
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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质量水平

方案

99%

折射率

n20/D 1.451 (lit.)

沸点

177 °C (lit.)
62-63 °C/12 mmHg (lit.)

mp

−1 °C (lit.)

密度

0.968 g/mL at 20 °C (lit.)

SMILES字符串

CN(C)C(=O)N(C)C

InChI

1S/C5H12N2O/c1-6(2)5(8)7(3)4/h1-4H3

InChI key

AVQQQNCBBIEMEU-UHFFFAOYSA-N

基因信息

human ... EPHX2(2053)
mouse ... Ephx2(13850)

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应用

  • 四甲基脲在介孔氧化铝合成中的作用:四甲基脲通过水热法合成介孔氧化铝,影响了孔结构和热稳定性(Ghosh et al., 2014)。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B - Skin Irrit. 2

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

167.0 °F - closed cup

闪点(°C)

75 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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F A Sylvester et al.
Infection and immunity, 64(4), 1420-1425 (1996-04-01)
Piliated Burkholderia (formerly Pseudomonas) cepacia from sputa of cys tic fibrosis patients in Toronto, Canada, were shown earlier to bind to purified mucins and to a protein receptor on epithelial cells via a 22-kDa adhesin located on unique cable pili.
Y L A Rezus et al.
Physical review letters, 99(14), 148301-148301 (2007-10-13)
We have used femtosecond midinfrared spectroscopy to study the orientational mobility of water molecules in the hydration shells of hydrophobic groups. Our results show that hydrophobic groups are surrounded by a number of water molecules that display much slower orientational
Klaas-Jan Tielrooij et al.
Journal of the American Chemical Society, 132(44), 15671-15678 (2010-10-19)
We study the influence of the amphipilic compound tetramethylurea (TMU) on the dynamical properties of water, using dielectric relaxation spectroscopy in the regime between 0.2 GHz and 2 THz. This technique is capable of resolving different water species, their relative
Haiyan Wei et al.
The journal of physical chemistry. B, 114(1), 557-568 (2009-11-26)
The effects of urea, tetramethyl urea (TMU), and trimethylamine N-oxide (TMAO) on the structure and dynamics of aqueous solutions are studied using molecular dynamics simulations. It was found that urea has little effects on the water-water hydrogen-bond length and angle
Marcelo A da Silva et al.
Journal of colloid and interface science, 289(2), 394-401 (2005-06-07)
In this work, the gelation kinetics and fractal character of lysozyme gel matrices developed in tetramethylurea (TMU)-water media were investigated. Gelation times were determined from the temporal crossover point between the storage, G', and loss, G'', moduli, as a function

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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