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Merck

105228

Sigma-Aldrich

1,1,1,3,3,3-六氟-2-丙醇

≥99%

别名:

HFP, 六氟异丙醇

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About This Item

线性分子式:
(CF3)2CHOH
CAS号:
分子量:
168.04
Beilstein:
1841007
EC號碼:
MDL號碼:
分類程式碼代碼:
12352104
PubChem物質ID:
NACRES:
NA.22
化驗:
≥99%

品質等級

化驗

≥99%

折射率

n20/D 1.275 (lit.)

bp

59 °C (lit.)

mp

−4 °C (lit.)

密度

1.596 g/mL at 25 °C (lit.)

官能基

fluoro
hydroxyl

SMILES 字串

OC(C(F)(F)F)C(F)(F)F

InChI

1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H

InChI 密鑰

BYEAHWXPCBROCE-UHFFFAOYSA-N

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一般說明

1,1,1,3,3,3-六氟-2-丙醇是溶液相肽化学溶剂。这种高电离能力的氟化极性溶剂可在无路易斯酸催化剂的情况下,通过共价试剂促进傅-克烷基化反应。它还可提高铑(I)催化的醚键连接的炔基二烯的[4 + 2]分子内环加成反应,以及炔基乙烯基环丙烷的[5 + 2]环加成反应效率。1,1,1,3,3,3-六氟-2-丙醇结合过氧化氢可团簇催化环辛烯和1-辛烯的环氧化作用。

應用

1,1,1,3,3,3-六氟-2-丙醇可用于制备六氟醇官能化甲基丙烯酸酯聚合物

象形圖

Health hazardCorrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Repr. 2 - Skin Corr. 1A - STOT RE 2 Oral

標靶器官

Central nervous system

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

No data available

閃點(°C)

No data available

個人防護裝備

Faceshields, Gloves, Goggles


历史批次信息供参考:

分析证书(COA)

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Kidney diseases are recognized as a major health problem, which affect 10% of the population. Because currently available therapies have many limitations, some tissue engineering strategies have been emerging as promising approaches in this field. In this work, porcine kidneys
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In fluorinated alcohols, the cationic Rh(I) species, which is derived from [Rh(COD)Cl]2 and AgSbF6, efficiently catalyzed intramolecular [4+2] cycloaddition reactions of ester-tethered 1,3-diene-8-yne derivatives. The catalytic system was also effective in intramolecular [5+2] cycloaddition reactions of ester-tethered omega-alkynyl vinylcyclopropane compounds.

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