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Merck

932698

Sigma-Aldrich

N4,N4,N4′,N4′-Tetra[(1,1′-biphenyl)-4-yl]-(1,1′-biphenyl)-4,4′-diamine

≥99% (HPLC)

别名:

N,N′-Tetra(4-biphenyl)benzidine, 4-Phenyl-n-(4-phenylphenyl)-n-[4-[4-(4-phenyl-n-(4-phenylphenyl)anilino)phenyl]phenyl]aniline, N,N,N′,N′-Tetrakis(4-biphenylyl)benzidine, N4,N4,N4′,N4′-Tetra(4-biphenylyl)-biphenyl-4,4′-diamine, BPBPA, [1,1′-Biphenyl]-4,4′-diamine, N4,N4,N4′,N4′-tetrakis([1,1′-biphenyl]-4-yl), [1,1′-Biphenyl]-4,4′-diamine, N4,N4,N4′,N4′-tetrakis([1,1′-biphenyl]-4-yl)

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1 G
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1 G
$469.00

About This Item

经验公式(希尔记法):
C60H44N2
分子量:
793.00
MDL编号:
UNSPSC代码:
12352116
NACRES:
NA.21

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等级

sublimed grade

质量水平

方案

≥99% (HPLC)

SMILES字符串

N(c5ccc(cc5)c6ccc(cc6)N(c9ccc(cc9)c%10ccccc%10)c7ccc(cc7)c8ccccc8)(c3ccc(cc3)c4ccccc4)c1ccc(cc1)c2ccccc2

InChI

1S/C60H44N2/c1-5-13-45(14-6-1)49-21-33-55(34-22-49)61(56-35-23-50(24-36-56)46-15-7-2-8-16-46)59-41-29-53(30-42-59)54-31-43-60(44-32-54)62(57-37-25-51(26-38-57)47-17-9-3-10-18-47)58-39-27-52(28-40-58)48-19-11-4-12-20-48/h1-44H

InChI key

WXAIEIRYBSKHDP-UHFFFAOYSA-N

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应用

N4,N4,N4′,N4′-Tetra[(1,1′-biphenyl)-4-yl]-(1,1′-biphenyl)-4,4′-diamine, also known as BPBPA, is a Hole Transport, Electron Blocking Layer (HTL / EBL) material. BPBPA is popularly used in optoelectronic devices, such as high efficiency and long lifetime light-emitting diode devices (organic LEDs, OLEDs).
N4,N4,N4′,N4′-Tetra[(1,1′-biphenyl)-4-yl]-(1,1′-biphenyl)-4,4′-diamine is used as a hole transport material or as a host material in the emissive layer of organic light-emitting diodes (OLEDs) devices. Its semiconducting properties suits for R&D studies in organic field-effect transistors(OFETs) and thin-film transistors (TFTs).

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Do Sik Kim et al.
ACS applied materials & interfaces, 12(17), 19737-19745 (2020-04-18)
Four electron transport type hosts withstanding the positive polaron stress were synthesized using the benzo[4,5]thieno[3,2-d]pyrimidine core to develop high triplet energy hosts. Four benzo[4,5]thieno[3,2-d]pyrimidine-derived hosts, 4-(9H-carbazol-9-yl)-2-(3-(triphenylsilyl)phenyl)benzo[4,5]thieno[3,2-d]pyrimidine (CzBTPmSi), 2,4-di(9H-carbazol-9-yl)benzo[4,5]thieno[3,2-d]pyrimidine (2CzBTP), 2-(9H-carbazol-9-yl)-4-(3-(triphenylsilyl)phenyl)benzo[4,5]thieno[3,2-d]pyrimidine (mSiBTPCz), and 2,4-bis(3-(triphenylsilyl)phenyl)benzo[4,5]thieno[3,2-d]pyrimidine (2mSiBTP), were designed to have either the
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