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![N-([1,1′-Biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine ≥97%](/deepweb/assets/sigmaaldrich/product/structures/334/842/a358db6a-5ec8-4c88-902f-856ed7d79fb6/640/a358db6a-5ec8-4c88-902f-856ed7d79fb6.png)
等级
sublimed grade
质量水平
描述
µh ≈ 1.0 x 10-3cm2V-1s-1
方案
≥97% (HPLC)
缺失
0.5% TGA, >290°C (weigh loss)
mp
186 °C
溶解性
THF: soluble
chloroform: soluble
toluene: soluble
λmax
305 nm±5 nm in THF
荧光
λem 370 nm±10 nm in dichloromethane
轨道能量
HOMO 5.5 eV
LUMO 2.0 eV
SMILES字符串
Cc1ccc(cc1)N(c2ccc(C)cc2)c3ccc(cc3)C4(CCCCC4)c5ccc(cc5)N(c6ccc(C)cc6)c7ccc(C)cc7
InChI
1S/C46H46N2/c1-34-8-20-40(21-9-34)47(41-22-10-35(2)11-23-41)44-28-16-38(17-29-44)46(32-6-5-7-33-46)39-18-30-45(31-19-39)48(42-24-12-36(3)13-25-42)43-26-14-37(4)15-27-43/h8-31H,5-7,32-33H2,1-4H3
InChI key
ZOKIJILZFXPFTO-UHFFFAOYSA-N
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应用
Di-[4-(N,N-di-p-tolyl-amino)-phenyl]cyclohexane, also known as TAPC, is a solution-processable Hole Transport, Electron Blocking Layer (HTL / EBL) benzene compound material with a μh around 1.0 × 10−3 cm2 V−1 s−1. It has been explored in several optoelectronic devices, especially in diodes such as efficient and stable lead-free halide double perovskites diodes.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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White light generation combining emissions from exciplex, excimer and electromer in TAPC-based organic light-emitting diodes
Yang, Shengyi et al.
Chemical Physics Letters, 484, 54-58 (2009)
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The combination of rigid acridine donor and 1,8-naphthalimide acceptor has afforded two orange-red emitters of NAI-DMAC and NAI-DPAC with high rigidity in molecular structure and strongly pretwisted charge transfer state. Endowed with high photoluminescence quantum yields (ΦPL ), distinct thermally
Wei Li et al.
Angewandte Chemie (International ed. in English), 58(33), 11301-11305 (2019-06-14)
Blue thermally activated delayed fluorescence (TADF) emitters that can simultaneously achieve high efficiency in doped and nondoped organic light-emitting diodes (OLEDs) are rarely reported. Reported here is a strategy using a tri-spiral donor for such versatile blue TADF emitters. Impressively
Jiajun Luo et al.
Nature, 563(7732), 541-545 (2018-11-09)
Lighting accounts for one-fifth of global electricity consumption1. Single materials with efficient and stable white-light emission are ideal for lighting applications, but photon emission covering the entire visible spectrum is difficult to achieve using a single material. Metal halide perovskites
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