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796557

Stahl Aerobic Oxidation ABNO solution

Name: Stahl Aerobic Oxidation ABNO solution
Brand: ALDRICH

0.04M ABNO in Acetonitrile, Solution for Oxidation of Primary and Secondary Alcohols

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About This Item

分類程式碼代碼:

12352000

NACRES:

NA.22

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描述

Freezing Point: 44.6°F

形狀

liquid

反應適用性

reagent type: oxidant

折射率

n/D 1.357

密度

0.796 at 25 °C

儲存溫度

2-8°C

一般說明

Stahl Aerobic Oxidation ABNO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and ABNO for the oxidation of primary and secondary alcohols.

應用

This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group.

訊號詞

Danger

危險聲明

H225,H302 + H312 + H332,H315,H318,H361d

防範說明

P210 - P280 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

43.5 °F

閃點（°C）

6.38 °C

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Lauber, MB, and Stahl, SS.

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Stable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl-Catalyzed Aerobic Alcohol Oxidation.

Janelle E Steves et al.

The Journal of organic chemistry, 80(21), 11184-11188 (2015-10-13)

Two solutions, one consisting of bpy/TEMPO/NMI and the other bpy/ABNO/NMI (bpy =2,2'-bipyridyl; TEMPO = 2,2,6,6-tetramethylpiperidine N-oxyl, ABNO = 9-azabicyclo[3.3.1]nonane N-oxyl; NMI = N-methylimidazole), in acetonitrile are shown to have good long-term stability (≥1 year) under air at 5 °C. The

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Janelle E Steves et al.

Journal of the American Chemical Society, 135(42), 15742-15745 (2013-10-17)

Cu/TEMPO catalyst systems promote efficient aerobic oxidation of sterically unhindered primary alcohols and electronically activated substrates, but they show reduced reactivity with aliphatic and secondary alcohols. Here, we report a catalyst system, consisting of ((MeO)bpy)Cu(I)(OTf) and ABNO ((MeO)bpy = 4,4'-dimethoxy-2,2'-bipyridine;

商品

Aerobic Alcohol Oxidation Solutions

Alcohol oxidation yields aldehydes and ketones, crucial intermediates in organic synthesis.

文件

Stahl Aerobic Oxidation ABNO solution