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Merck
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426369

Sigma-Aldrich

TEMPO

purified by sublimation, 99%

别名:

2,2,6,6-四甲基哌啶氧化物, 2,2,6,6-四甲基哌啶-1-氧自由基, TEMPO

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About This Item

经验公式（希尔记法）:
C9H18NO
CAS号:
2564-83-2
分子量:
156.25
Beilstein:
1422418
EC號碼:
219-888-8
MDL號碼:
MFCD00009599
分類程式碼代碼:
12352119
PubChem物質ID:
24866699
NACRES:
NA.22

化驗

99%

形狀

solid

純化經由

sublimation

反應適用性

reagent type: oxidant

mp

36-38 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CC1(C)CCCC(C)(C)N1[O]

InChI

1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3

InChI 密鑰

QYTDEUPAUMOIOP-UHFFFAOYSA-N

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相关类别

一般說明

对于使用 NMP 引发剂的合成方案，由 Karen Wooley 教授提供，请访问我们的 技术聚光灯。

應用

利用 TEMPO（2,2,6,6-四甲基-1-哌啶氧基）捕集过氧苯甲酰自由基。利用 TEMPO 介导氧化法制备了耐水纳米纤维纤维素 (NFC) 膜。
稳定的硝基氧自由基可用于控制活性聚合

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314,H412

危險分類

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 2

閃點（°F）

152.6 °F - closed cup

閃點（°C）

67 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

分析证书(COA)

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Akira Isogai et al.
Nanoscale, 3(1), 71-85 (2010-10-20)
Native wood celluloses can be converted to individual nanofibers 3-4 nm wide that are at least several microns in length, i.e. with aspect ratios>100, by TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation and successive mild disintegration in water. Preparation methods and fundamental characteristics
Jessica M Hoover et al.
Journal of the American Chemical Society, 135(6), 2357-2367 (2013-01-16)
Homogeneous Cu/TEMPO catalyst systems (TEMPO = 2,2,6,6-tetramethylpiperidine-N-oxyl) have emerged as some of the most versatile and practical catalysts for aerobic alcohol oxidation. Recently, we disclosed a (bpy)Cu(I)/TEMPO/NMI catalyst system (NMI = N-methylimidazole) that exhibits fast rates and high selectivities, even
Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator.
Lee NS and Wooley KL.
Material Matters, 5, 8-15 (2010)
Soham Maity et al.
Journal of the American Chemical Society, 135(9), 3355-3358 (2013-02-15)
Nitroolefin is a common and versatile reagent. Its synthesis from olefin is generally limited by the formation of mixture of cis and trans compounds. Here we report that silver nitrite (AgNO2) along with TEMPO can promote the regio- and stereoselective
Xinwang Cao et al.
Carbohydrate polymers, 90(2), 1075-1080 (2012-07-31)
Cellulose nanowhiskers is a kind of renewable and biocompatible nanomaterials evoke much interest because of its versatility in various applications. Here, for the first time, a novel controllable fabrication of cellulose nanowhiskers from jute fibers with a high yield (over
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