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Merck

517135

Sigma-Aldrich

碳酸二乙酯

greener alternative

anhydrous, ≥99%

别名:

Eufin, H-DEC, 双元油

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100 ML
$34.00
1 L
$127.00

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国内现货,预计发货时间2025年4月25日详情


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100 ML
$34.00
1 L
$127.00

About This Item

线性分子式:
(C2H5O)2CO
CAS号:
分子量:
118.13
Beilstein:
956591
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$34.00


国内现货,预计发货时间2025年4月25日详情


获取大包装报价

等级

anhydrous

质量水平

蒸汽密度

4.1 (vs air)

蒸汽压

10 mmHg ( 23.8 °C)
59 mmHg ( 37.8 °C)

方案

≥99%

环保替代产品特性

Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

<0.002% water
<0.005% water (100 mL)

折射率

n20/D 1.384 (lit.)

沸点

126-128 °C (lit.)

mp

−43 °C (lit.)

溶解性

water: insoluble

密度

0.975 g/mL at 25 °C (lit.)

官能团

carbonate

环保替代产品分类

SMILES字符串

O=C(OCC)OCC

InChI

1S/C5H10O3/c1-3-7-5(6)8-4-2/h3-4H2,1-2H3

InChI key

OIFBSDVPJOWBCH-UHFFFAOYSA-N

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一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。本产品是一种更环保的试剂。点击此处以获取更多信息。
碳酸二乙酯是一种二烷基碳酸酯。[1]以尿素和乙醇为原料合成碳酸二乙酯 (DEC)。[2]

应用

碳酸二乙酯可用于以下研究:
  • β-环糊精的合成-烯胺酯。[3]
  • 用 TBD 锚定在 MCM-41 硅石上制备的杂化有机无机材料与脂肪胺或醇反应合成氨基甲酸酯和不对称烷基碳酸酯。[4]
  • 作为钌催化的溶剂,通过芳基卤化物直接官能化芳烃 C-H 键。[5]
  • 研制商品化锂离子电池液体电解质。[6]
  • 纤维素的均相烷氧羰基化。[1]

特点和优势

绿色化学品

象形图

Flame

警示用语:

Warning

危险声明

危险分类

Flam. Liq. 3

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

77.0 °F - closed cup

闪点(°C)

25 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Catalytic activity of MCM-41-TBD in the selective preparation of carbamates and unsymmetrical alkyl carbonates from diethyl carbonate.
Carloni S, et al.
J. Catal., 205(1), 199-204 (2002)
A versatile route to β-enamino esters by acylation of lithium enamines with diethyl carbonate or benzyl chloroformate.
Bartoli G, et al.
Tetrahedron, 51(31), 8613-8622 (1995)
Synthesis of diethyl carbonate by catalytic alcoholysis of urea.
Wang D, et al.
Fuel Processing Technology, 88(8), 807-812 (2007)
Sara R Labafzadeh et al.
ChemSusChem, 8(1), 77-81 (2014-11-08)
Dialkylcarbonates are viewed as low-cost, low-toxicity reagents, finding application in many areas of green chemistry. Homogeneous alkoxycarbonylation of cellulose was accomplished by applying dialkycarbonates (dimethyl and diethyl carbonate) in the ionic liquid-electrolyte trioctylphosphonium acetate ([P8881 ][OAc])/DMSO or 1-ethyl-3-methylimidazolium acetate ([emim][OAc]).
Diethyl carbonate as a solvent for ruthenium catalysed C-H bond functionalisation.
Arockiam P, et al.
Green Chemistry, 11(11), 1871-1875 (2009)

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Solid oxide fuel cells and electrolyzers show potential for chemical-to-electrical energy conversion, despite early development stages.

固体氧化物燃料电池(SOFC)和固体氧化物电解池(SOE)正处于早期开发阶段,但性能发展已有望实现电化学能量的转化。

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相关内容

Green chemicals evaluation aligns with the 12 Principles of Green Chemistry, emphasizing resource efficiency and hazard reduction.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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