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化驗
97%
折射率
n20/D 1.483 (lit.)
bp
254 °C (lit.)
密度
1.1 g/mL at 25 °C (lit.)
SMILES 字串
O=C1CCCCC(=O)C1
InChI
1S/C7H10O2/c8-6-3-1-2-4-7(9)5-6/h1-5H2
InChI 密鑰
DBOVMTXPZWVYAQ-UHFFFAOYSA-N
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves
Allen Y Hong et al.
Tetrahedron, 67(52), 10234-10248 (2012-02-22)
General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedded in numerous natural products have been developed. The central stereoselective transformation in our divergent strategies is the enantioselective decarboxylative alkylation of seven-membered β-ketoesters to form α-quaternary vinylogous esters. Recognition
Evan A Sims et al.
Tetrahedron letters, 52(16), 1871-1873 (2011-06-29)
We report the large-scale synthesis of 1,3-cyclooctanedione in five steps with 29% yield. This molecule is a synthetic precurser to difluorinated cyclooctyne, which participates in a bioorthogonal copper-free click reaction with azides. The final step demonstrates the first successful application
Michael additions of 1, 3-cycloalkanediones to dimethyl acety-lenedicarboxylate.
Hrnciar P, et al.
Chemical Papers, 43(1), 87-95 (1989)
Methylation of 1, 3-cyclopentanedione, 1, 3-cyclohexanedione, and 1, 3-cycloheptanedione with iodomethane in aprotic solvents in the absence and in the presence of 18-crown-6.
Sraga J and Hrnciar P.
Chemical Papers, 35(1), 119-126 (1981)
Michael addition of 1, 3-cyclopentanedione, 1, 3-cyclohexanedione and 1, 3-cycloheptanedione to 1-(X-phenyl)-2-nitroethylenes.
Hrnciar P and Culak I.
Collection of Czechoslovak Chemical Communications, 49(6), 1421-1431 (1984)
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