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Merck
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文件

697575

Sigma-Aldrich

(乙腈)[(2-联苯)二叔丁基膦]六氟锑酸金(I)

别名:

JohnPhos Au(MeCN)SbF6

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About This Item

经验公式（希尔记法）:
C22H30AuF6NPSb
CAS号:
866641-66-9
分子量:
772.17
MDL號碼:
MFCD11045449
分類程式碼代碼:
12161600
PubChem物質ID:
329761933
NACRES:
NA.22

形狀

solid

品質等級

100

反應適用性

core: gold
reagent type: catalyst

mp

198-203 °C (D)

SMILES 字串

[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C

InChI

1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6

InChI 密鑰

ADQOZROJMVWPRI-UHFFFAOYSA-H

相关类别

一般說明

(乙腈)[(2-联苯)二叔丁基膦]六氟锑酸金(I) 是一种磷化氢连接的金（I）复合物。它可用作多米诺反应的催化剂，用于形成C–C、C–N和C–O 键，因为其容易激活C=C 和C≡C键，从而产生独特的重排结构或者与各种亲核试剂反应。金催化剂提供了一种温和地构建复杂化学结构的良好方法，采用其它反应模式则难以实现这一点。

應用

金催化剂— 21世纪 ′淘金热′

象形圖

Exclamation markEnvironment
GHS07,GHS09

訊號詞

Warning

危險聲明

H302 + H332,H411

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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The research of the Echavarren group centers on the development of new reactions based on the use of electrophilic complexes of Au(I), Pt(II), and other transition metals as catalysts and their applications in organic synthesis of complex, biologically active molecules. The Echavarren group is also examining new strategies for the synthesis of polyarenes of interest in material science. In particular, they are interested in the ready construction of C-60 skeletons using reactions catalyzed by Pd(0) and other transition metals.

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