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方案
98%
mp
252-255 °C (lit.)
SMILES字符串
Oc1c(Br)c(Br)c(O)c(Br)c1Br
InChI
1S/C6H2Br4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11/h11-12H
InChI key
DTFQULSULHRJOA-UHFFFAOYSA-N
一般描述
Tetrabromohydroquinone (TBHQ), also known as 2,3,5,6-tetrabromohydroquinone, can be synthesized by reacting bromanil with phenyl phosphine.[1] It crystallizes in the monoclinic space group, P21/n. The effect of C-Br group on the crystal structure of TBHQ has been investigated.[2] Its role in causing green luminescence in Ptychodera flava has been investigated.[3]
应用
Tetrabromohydroquinone may be used in the synthesis of thermoresponsive branched oligoethylene glycol dendrimers.[4]
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Mona A Abdel-Rahman et al.
European journal of medicinal chemistry, 69, 848-854 (2013-10-15)
Three interesting thermoresponsive branched oligoethylene glycol dendrimers based on tetrabromohydroquinone were efficiently synthesized from tetrabromohydroquinone and three different oligoethylene glycol derivatives. By visual inspection, all these dendrimers are water-soluble at room temperature. The thermoresponsive behaviors were investigated by using UV/vis
Akira Kanakubo et al.
Luminescence : the journal of biological and chemical luminescence, 20(6), 397-400 (2005-06-21)
2,3,5,6-Tetrabromohydroquinone was isolated as a luminous substance from Ptychodera flava. This compound emitted light after addition of hydrogen peroxide under basic conditions. Since hydroquinone had no fluorescence, further investigation by spectral analysis revealed that riboflavin was the only possible light
A comparative study of the crystal structures of tetrahalogenated hydroquinones and ?-hydroquinone.
Thalladi VR, et al.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 55(6), 1005-1013 (1999)
Reaction of phenylphosphine with p-quinones.
Pudovik AN, et al.
Russian Chemical Bulletin, 27(7), 1450-1452 (1978)
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