449563

硼烷二苯基膦复合物

98%

• 别名: (Diphenylphosphine)trihydroboron
• 线性分子式: (C₆H₅)₂PH·BH₃
• CAS号: 41593-58-2
• 分子量: 200.02
• MDL编号: MFCD00274254
• UNSPSC代码: 12352002
• PubChem化学物质编号: 24868492
• NACRES: NA.22

属性

• 质量水平: 100
• 方案: 98%
• 表单: solid
• 反应适用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Reductions; reagent type: reductant
• 沸点: 148-150 °C/10 mmHg (lit.)
• mp: 47-50 °C (lit.)
• 官能团: phosphine
• SMILES字符串: B.[H]P(c1ccccc1)c2ccccc2
• InChI: 1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
• InChI key: XUFGOLYVDOBYLK-UHFFFAOYSA-N

说明

应用

Reactant for:

• Nucleophilic addition reactions (anion)
• Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
• Deprotonation reactions
• Catalytic coupling with alkynyl bromides
• Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
• Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
• Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

安全信息

• 象形图: GHS02
• 警示用语：: Danger
• 危险声明: H261
• 预防措施声明: P231 + P232 - P422
• 危险分类: Water-react 2
• 储存分类代码: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges