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Merck

F408

Sigma-Aldrich

二茂铁

98%

别名:

二环戊二烯铁, 双环戊二烯基铁

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About This Item

线性分子式:
Fe(C5H5)2
CAS号:
分子量:
186.03
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

0.03 mmHg ( 40 °C)

化驗

98%

反應適用性

core: iron
reagent type: catalyst

bp

249 °C (lit.)

mp

172-174 °C (lit.)

λmax

358 nm

儲存溫度

2-8°C

SMILES 字串

[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;

InChI 密鑰

DFRHTHSZMBROSH-UHFFFAOYSA-N

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應用

二茂铁(二环戊二烯基铁)可用于:
  • 用作不对称催化中的手性配体支架。
  • 染料敏化太阳能电池应用中的二茂铁基电解质。
  • 合成不对称二茂铁配体,可用作交叉偶联、氢化、烯丙基取代的催化剂。
  • 通过化学气相沉积法合成二维六方有序介孔碳(CMK-5),用作甲醇氧化的催化剂载体。
  • 合成二茂铁与富勒烯的分子杂化物(巴基二茂铁)。
  • 制备二茂铁盐,用作温和氧化剂。

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation

標靶器官

Liver

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Adopting supramolecular chemistry for immobilization of proteins is an attractive strategy that entails reversibility and responsiveness to stimuli. The reversible and oriented immobilization and micropatterning of ferrocene-tagged yellow fluorescent proteins (Fc-YFPs) onto β-cyclodextrin (βCD) molecular printboards was characterized using surface
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Rarely reported low-cost molybdenum boride and carbide microparticles, both of which are available in abundant quantities due to their widespread use in industry, adsorb at aqueous acid-1,2-dichloroethane interfaces and efficiently catalyse the hydrogen evolution reaction in the presence of the
CMK-5 mesoporous carbon synthesized via chemical vapor deposition of ferrocene as catalyst support for methanol oxidation
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Transparent wood composites, with their high strength and toughness, thermal insulation, and excellent transmissivity, offer a route to replace glass for diffusely transmitting windows. Here, conjugated-polymer-based electrochromic devices (ECDs) that switch on-demand are demonstrated using transparent wood coated with poly(3,4-ethylenedioxythiophene):poly(styrene

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