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Merck

C39601

Sigma-Aldrich

氯代二苯基膦

96%

别名:

P-氯代二苯基膦, ClPPh2, PPh2Cl, 二苯基氯化膦

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25 G
$103.00
100 G
$221.00
500 G
$652.00

$103.00


国内现货,预计发货时间2025年4月21日详情


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25 G
$103.00
100 G
$221.00
500 G
$652.00

About This Item

线性分子式:
(C6H5)2PCl
CAS号:
分子量:
220.63
Beilstein:
512032
EC 号:
MDL编号:
UNSPSC代码:
12352128
PubChem化学物质编号:
NACRES:
NA.22

$103.00


国内现货,预计发货时间2025年4月21日详情


获取大包装报价

蒸汽密度

7.8 (vs air)

质量水平

方案

96%

表单

liquid

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

折射率

n20/D 1.636 (lit.)

沸点

320 °C (lit.)

密度

1.194 g/mL at 25 °C
1.229 g/mL at 25 °C (lit.)

官能团

phosphine

SMILES字符串

ClP(c1ccccc1)c2ccccc2

InChI

1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

XGRJZXREYAXTGV-UHFFFAOYSA-N

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一般描述

Ph2PCl 是一种用于交叉偶联反应和将 Ph2P 基团引入分子的有效试剂。[1]

应用

用于合成各种膦的前体。
用于通过芳基邻锂化反应引入二苯基氧膦基部分。[2][3]

象形图

CorrosionExclamation mark

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

补充剂危害

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 1

闪点(°F)

280.4 °F

闪点(°C)

138 °C

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chemical & Pharmaceutical Bulletin, 41, 1149-1149 (1993)
Journal of the Chemical Society. Perkin Transactions 1, 1433-1433 (1993)
Synlett, 3150-3150 (2006)
Resorcinarenyl-Phosphines in Suzuki--Miyaura Cross-Coupling Reactions of Aryl Chlorides
Monnereau L, et al.
European Journal of Inorganic Chemistry, 2014, 1364-1372 (2014)
Synthesis, 3631-3631 (2006)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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