419206

苄基(三苯基膦)乙酸酯

97%

• 别名: (Benzyloxycarbonylmethylene)triphenylphosphorane, 2-(Triphenylphosphoranylidene)acetic acid phenylmethyl ester
• 线性分子式: (C₆H₅)₃P=CHCO₂CH₂C₆H₅
• CAS号: 15097-38-8
• 分子量: 410.44
• MDL编号: MFCD00191787
• UNSPSC代码: 12352108
• PubChem化学物质编号: 24866098
• NACRES: NA.22

属性

• 方案: 97%
• 反应适用性: reaction type: C-C Bond Formation
• mp: 120-122 °C (lit.)
• 官能团: ester; phenyl; phosphine
• SMILES字符串: O=C(OCc1ccccc1)C=P(c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C27H23O2P/c28-27(29-21-23-13-5-1-6-14-23)22-30(24-15-7-2-8-16-24,25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20,22H,21H2
• InChI key: INKMLGJBBDRIQR-UHFFFAOYSA-N

说明

应用

Reactant for:

• Tributylphosphine-mediated vinylogous Wittig reactions
• Synthesis of 1,2-dioxanes for antitrypanosomal activity
• Organocatalytic Michael-type reactions / Wittig reactions of phosphorus ylides and unsaturated ketones
• Stereoselective phosphine-catalyzed cycloaddition to form spirocyclopenteneoxindoles
• Enantioselective synthesis of pantothenic acid
• Preparation of phosphorus ylides from phosphoranes and acetic anhydride

安全信息

• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: Eyeshields, Gloves, type N95 (US)