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Merck

B32807

Sigma-Aldrich

苄基三苯基氯化膦

99%

别名:

BTPPC, NSC 116712, 三苯基(苯基甲基)氯化鏻

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25 G
$61.70
100 G
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About This Item

线性分子式:
C6H5CH2P(Cl)(C6H5)3
CAS号:
分子量:
388.87
Beilstein:
3599868
EC 号:
MDL编号:
UNSPSC代码:
12352107
PubChem化学物质编号:
NACRES:
NA.22

$61.70


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方案

99%

表单

powder

反应适用性

reaction type: C-C Bond Formation

mp

≥300 °C (lit.)

SMILES字符串

[Cl-].C(c1ccccc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C25H22P.ClH/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1

InChI key

USFRYJRPHFMVBZ-UHFFFAOYSA-M

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应用

管状天然埃洛石/氟弹性体纳米复合材料交联剂

用于合成以下物质的反应物:
  • 叠氮化铂氯四唑配合物
  • 维蒂希烯烃化反式芪和肉桂酸酯
  • 用于治疗骨关节炎的ADAM-TS4和ADAM-TS5的非手性羟基甲酰胺抑制剂
  • 用作光驱动分子制动器的戊三烯

用于形成群岛结构的反应物,继而形成石油沥青质
苄基三苯基氯化鏻可用作反应物,以便:
  • 通过叠氮基化合成铂氯-四唑配合物。[1]
  • 通过维蒂希烯烃化合成反式芪和肉桂酸酯。[2]
  • 用于治疗骨关节炎的ADAM-TS4和ADAM-TS5的非手性羟基甲酰胺抑制剂。[3]
  • 用作光驱动分子制动器的戊三烯。[4]
  • 用于形成石油沥青质的群岛结构。[5]


它也用作管状天然埃洛石/氟弹性体纳米复合材料交联剂。[6]

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT RE 1 - STOT SE 3

靶器官

Lungs,nasal cavity, Respiratory system

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

572.0 °F - closed cup

闪点(°C)

300 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the shelf life for this product?

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

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