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377171

Sigma-Aldrich

1,2-环氧己烷

97%

别名:

1-己烯氧化物, 丁基环氧乙烷

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$96.30
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$358.00

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25 G
$96.30
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About This Item

经验公式（希尔记法）:
C6H12O
CAS号:
1436-34-6
分子量:
100.16
Beilstein:
102568
EC 号:
215-864-6
MDL编号:
MFCD00005154
UNSPSC代码:
12162002
PubChem化学物质编号:
24863209
NACRES:
NA.23

$96.30

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质量水平

100

方案

97%

表单

liquid

杂质

<3% acetic acid

折射率

n20/D 1.406 (lit.)

沸点

118-120 °C (lit.)

密度

0.831 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

CCCCC1CO1

InChI

1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3

InChI key

WHNBDXQTMPYBAT-UHFFFAOYSA-N

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应用

  • 聚（环氧氯丙烷-co-1, 2-环氧己烷）–一种前景良好的用于叠氮聚合物成型固化（cast-cure）的前体：讨论了采用环氧氯丙烷和1, 2-环氧己烷合成的一种共聚物，研究目的在于开发一种用于能量应用的内增塑剂（TM Klapötke, 2016)。
  • 以小晶体合成的多级孔沸石（hierarchically porous zeolite） TS-1 及其1-己烯环氧化反应性能：该研究考察了1, 2-环氧己烷在各种化学行业用中间体制备中的催化性能（M Zhang et al., 2021）。
  • 利用来自红球菌 ST‐10（RhSMO）的苯乙烯单加氧酶进行手性环氧烷烃的生物生产：关注了利用生物催化剂进行（S）-1,2-环氧己烷的酶法生产，重点介绍了其在手性环氧烷烃制备中的潜力（H Toda et al., 2014)。
  • 用于增进1-己烯环氧化性能的、硅岛（Silica island） 调节TS‐1的外部T位环境（external Ti‐site environment）：探索了利用TS-1 改性催化剂改善环氧化反应中1-己烯的性能（（J Yuan et al., 2023）。
  • 采用非均相半导体材料进行1-己烯的气相光催化氧化：描述了通过气相光催化氧化进行1, 2-环氧己烷的合成，重点关注了过程的选择性和效率（EA Kamba et al., 2023）。

象形图

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GHS02,GHS07

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Danger

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

59.0 °F - closed cup

闪点(°C)

15 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBL0611
STBK8559
STBL0016
STBK1062
STBH2749

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W J Choi et al.
Applied microbiology and biotechnology, 54(5), 641-646 (2000-12-29)
A two-phase membrane bioreactor was developed to continuously produce enantiopure epoxides using the epoxide hydrolase activity of Rhodotorula glutinis. An aqueous/organic cascade, hydrophilic, hollow-fiber membrane bioreactor was used: (1) to carry out large-scale resolution of epoxides, (2) to continuously extract
Ijaz Gul et al.
Journal of biotechnology, 311, 19-24 (2020-02-19)
Halohydrin dehalogenases (HHDHs) are valuable biocatalysts involved in the synthesis of β-substituted alcohols via their nucleophile-mediated ring-opening activity. To use directed evolution to unleash the latent potential of HHDHs for the synthesis of β-substituted alcohols, we report a high-throughput assay
Thomas Klein et al.
Dalton transactions (Cambridge, England : 2003), 49(28), 9820-9834 (2020-07-08)
Al nanoparticles represent one of the most challenging classes of metal nanoparticles in synthesis and handling due to their high chemical reactivity and their affinity to oxidation. A promising wet chemical preparation route is the catalytic decomposition of alane adducts.
Allison C Vander Wall et al.
Environmental science. Processes & impacts, 22(1), 66-83 (2019-11-02)
Secondary organic aerosol (SOA) particles are ubiquitous in air and understanding the mechanism by which they grow is critical for predicting their effects on visibility and climate. The uptake of three organic nitrates into semi-solid SOA particles formed by α-pinene
Zhimin Xue et al.
Chemistry, an Asian journal, 12(17), 2271-2277 (2017-06-20)
Development of inexpensive, easily prepared, non-toxic, and efficient catalysts for the cycloaddition of CO
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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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