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Merck

230197

Sigma-Aldrich

三乙基硅烷

99%

别名:

NSC 93579, 三乙基硅烷

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About This Item

线性分子式:
(C2H5)3SiH
CAS号:
分子量:
116.28
Beilstein:
1098278
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

liquid

反應適用性

reagent type: reductant

折射率

n20/D 1.412 (lit.)

bp

107-108 °C (lit.)

密度

0.728 g/mL at 25 °C (lit.)

SMILES 字串

CC[SiH](CC)CC

InChI

1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3

InChI 密鑰

AQRLNPVMDITEJU-UHFFFAOYSA-N

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應用

作为以下研究的催化剂:
  • 用于合成治疗疼痛的螺羟吲哚类 NaV1.7阻断剂
  • 氧化还原引发的阳离子聚合
  • 环十二酮肟的Beckmann重排
  • 烯酮和丙二烯的区域选择性还原偶联

苯乙烯催化剂聚合后的催化剂再活化

有机硅闪点预测的相关研究
多功能还原剂
用于 2-色原烷醇还原反应的研究;与 TES 可观察到顺式选择性。

相關產品

产品编号
说明
价格

象形圖

FlameExclamation mark

訊號詞

Danger

危險分類

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

21.2 °F

閃點(°C)

-6 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Organic letters, 8(21), 4711-4714 (2006-10-06)
[reaction: see text] Reduction of C5-substituted 2-hydroxychromans selectively provides 2,4-cis-chromans using large silane reductants and 2,4-trans-chromans using the smaller silane PhSiH(3). The stereochemical outcome has been rationalized on the basis of a Curtin-Hammett kinetic situation arising from hydride delivery to
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