332364

烯丙基三苯基锡

97%

• 别名: 2-丙烯基-三苯基锡, 丙烯基三苯基锡
• 线性分子式: CH₂=CHCH₂Sn(C₆H₅)₃
• CAS号: 76-63-1
• 分子量: 391.09
• Beilstein: 3612762
• EC 号: 200-975-4
• MDL编号: MFCD00048162
• UNSPSC代码: 12352103
• PubChem化学物质编号: 24859890
• NACRES: NA.22

属性

• 方案: 97%
• 表单: solid
• mp: 71-74 °C (lit.)
• SMILES字符串: C=CC[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;
• InChI key: NDUYAGLANMHJHF-UHFFFAOYSA-N

说明

一般描述

Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.[1]

应用

Allyltriphenylstannane can be used:

• As a reagent in the C-H phenylation of azoles catalyzed by palladium.[2]
• As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)₃.[3]
• As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.[4]

安全信息

• 象形图: GHS06,GHS09
• 警示用语：: Danger
• 危险声明: H301 + H311 + H331,H410
• 预防措施声明: P261 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• 危险分类: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• 储存分类代码: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: Eyeshields, Gloves, type N95 (US)