If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
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蒸汽密度
9 (vs air)
品質等級
蒸汽壓力
10 mmHg ( 10 °C)
18.6 mmHg ( 20 °C)
20 mmHg ( 22 °C)
化驗
98%
形狀
liquid
反應適用性
core: tin
reagent type: Lewis acid
reagent type: catalyst
bp
114 °C (lit.)
mp
−33 °C (lit.)
密度
2.226 g/mL at 25 °C (lit.)
SMILES 字串
Cl[Sn](Cl)(Cl)Cl
InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
InChI 密鑰
HPGGPRDJHPYFRM-UHFFFAOYSA-J
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一般說明
應用
- 反式 β-单环黄素转铁酸的环化以形成去甲肾上腺素。[2]
- 形成芳族化合物（如噻吩、萘和间苯三酚三甲醚）的C-糖苷。[3]
- 3-乙氧基环丁酮和烯丙基三烷基硅烷的缩甲醛[4 + 2]环加成，以形成3-乙氧基-5-[（三烷基甲硅烷基）甲基]环己-1-酮。[4]
- δ-烷氧基苯基锡烷与醛的非对映选择性反应，以形成1,5-二醇衍生物。[5]
SnCl4的其他应用：
- SnCl4-2,6-二烷氧基酚配合物可以催化聚合物的环化，例如催化4-（均三烯丙基）甲苯形成 反式- 稠合三环化合物。[6]
- SnCl4 可以在邻-氨基苯甲酸与β-酮酯和β-烯胺腈分别形成4-氨基喹啉和4-氨基吡啶的反应过程中充当促进剂。[7]
- SnCl4-高氯酸银可为糖基化1-O-乙酰葡萄糖立体选择性提供有效催化体系。[8]
訊號詞
Danger
危險聲明
危險分類
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 1
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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