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Merck

296643

Sigma-Aldrich

(R)-(-)-仲丁胺

99%

别名:

(R)-(-)-2-氨基丁烷

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About This Item

线性分子式:
C2H5CH(NH2)CH3
CAS号:
分子量:
73.14
Beilstein:
1718761
EC號碼:
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22

化驗

99%

光學活性

[α]19/D −7.5°, neat

折射率

n20/D 1.393 (lit.)

bp

63 °C (lit.)

密度

0.72 g/mL at 25 °C (lit.)

SMILES 字串

CC[C@@H](C)N

InChI

1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3/t4-/m1/s1

InChI 密鑰

BHRZNVHARXXAHW-SCSAIBSYSA-N

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應用

(R)-(−)-sec-Butylamine can be used:
  • To prepare (R)-(−)-sec-butylbis(2-hydroxyethyl)amine, an intermediate for the synthesis of aminodiphosphine ligands.
  • As a substrate to demonstrate the stereochemistry of Mitsunobu reaction in the synthesis of secondary amines.
  • As a model compound in the study of singlet-triplet transitions in circular dichroism.

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

-2.2 °F - closed cup

閃點(°C)

-19 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles


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Detection of singlet-triplet transitions in circular dichroism. A study of 2-aminobutane
Basil A and Gedanken A
Journal of the American Chemical Society, 111(26), 9237-9238 (1989)
Synthesis of the New Chiral (R)-and (S)-Aminodiphosphine Ligands sec-Butylbis (2-(diphenylphosphino) ethyl) amine, sec-Butylbis (2-(dicyclohexylphosphino) ethyl) amine, and (alpha-Methylbenzyl) bis (2-(dicyclohexylphosphino) ethyl) amine and Their Organom
Bianchini C, et al.
Organometallics, 16(20), 4403-4414 (1997)
Stereospecific synthesis of secondary amines by the Mitsunobu reaction
Edwards ML, et al.
Tetrahedron Letters, 31(24), 3417-3420 (1990)

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