276146

三正己硅烷

95%

• 别名: NSC 139856
• 线性分子式: [CH₃(CH₂)₅]₃SiH
• CAS号: 2929-52-4
• 分子量: 284.60
• EC 号: 220-893-2
• MDL编号: MFCD00009519
• UNSPSC代码: 12352001
• PubChem化学物质编号: 24856494
• NACRES: NA.22

属性

• 方案: 95%
• 表单: solid
• 反应适用性: reagent type: reductant
• 折射率: n20/D 1.448 (lit.)
• 沸点: 160.5-161 °C (lit.)
• 密度: 0.799 g/mL at 25 °C (lit.)
• SMILES字符串: CCCCCC[SiH](CCCCCC)CCCCCC
• InChI: 1S/C18H40Si/c1-4-7-10-13-16-19(17-14-11-8-5-2)18-15-12-9-6-3/h19H,4-18H2,1-3H3
• InChI key: IBNSYFQZHBBNLR-UHFFFAOYSA-N

说明

应用

Reactant for:

• Enantioselective Si-H insertion
• Regio- and stereoselective oxidation into silanols
• Asymmetric carbenoid insertion of diazoacetates into the silicon-hydrogen bond
• Hydrosilylation of carbon dioxide

Catalyst for hydrodefluorination leading to the synthesis of hydrocarbons

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H302 + H312 + H332,H315,H319,H335
• 预防措施声明: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• 危险分类: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 1
• 闪点(°F): 235.4 °F - closed cup
• 闪点(°C): 113 °C - closed cup