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Merck

241911

Sigma-Aldrich

氯化钨(VI)

≥99.9% trace metals basis

别名:

六氯化钨

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10 G
$148.00
100 G
$526.00

$148.00


国内现货,预计发货时间2025年4月08日详情


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10 G
$148.00
100 G
$526.00

About This Item

线性分子式:
WCl6
CAS号:
分子量:
396.56
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

$148.00


国内现货,预计发货时间2025年4月08日详情


获取大包装报价

等级

for analytical purposes

质量水平

蒸汽压

43 mmHg ( 215 °C)

方案

≥99.9% trace metals basis

表单

powder

反应适用性

reagent type: catalyst
core: tungsten

杂质

≤1000.0 ppm Trace Metal Analysis

沸点

347 °C (lit.)

mp

275 °C (lit.)

密度

3.52 g/mL at 25 °C (lit.)

SMILES字符串

Cl[W](Cl)(Cl)(Cl)(Cl)Cl

InChI

1S/6ClH.W/h6*1H;/q;;;;;;+6/p-6

InChI key

KPGXUAIFQMJJFB-UHFFFAOYSA-H

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一般描述

氯化钨(VI)是一种高反应性结晶固体,常用于催化、钙钛矿太阳能电池和发光器件领域。它是一种抗磁性固体。但是,它具有很强的腐蚀性和氧化作用。

应用

氯化钨(VI)可用于:
  • 作为水热法合成钨纳米颗粒[1]和Mo掺杂海胆状W18O49纳米结构的原料。Mo-W18O49电催化剂对析氢反应(HER)表现出优异的电催化活性。[2]通过将Mo掺杂到富含缺陷的W18O49超薄纳米线中,证明它是光催化N2固定合成氨的极佳选择。[3]
  • 以高分子量两亲性嵌段共聚物为结构导向剂,合成孔径为11 nm的结晶性介孔WO3。这些材料在H2S气体传感方面表现出色。[4]
  • 水热合成法制备二硫化钨和WS2/还原氧化石墨烯(WS2/rGO)纳米片。WS2/rGO纳米片在析氢反应中表现出优异的电催化活性。
  • 生产WS2-纳米花@rGO和氮掺杂碳球@WS2复合材料作为负极材料,增强锂离子电池的电极性能。[5]
  • 作为掺杂剂,制造性能增强的钙钛矿太阳能电池用TiO2致密层。[6]
  • 作为催化剂制备具有微胶囊的自修复环氧树脂复合材料。[7]
  • 作为叔烷基酰胺转酰胺反应的催化剂。[8]

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tungsten-Catalyzed Transamidation of Tertiary Alkyl Amides
Fang-Fang Feng, et al.
ACS Catalysis, 11, 7070-7079 (2021)
Mo doping induced more active sites in urchin-like W18O49 nanostructure with remarkably enhanced performance for hydrogen evolution reaction
Xing Zhong, et al.
Advanced Functional Materials , 26, 5778-5786 (2016)
Mild solution-processed metal-doped TiO2 compact layers for hysteresis-less and performance-enhanced perovskite solar cells
Chao Liang, et al.
Journal of Power Sources, 372, 235-244 (2017)
Tetrahedron Letters, 47, 5167-5167 (2006)
Liyan Zhou et al.
Scientific reports, 9(1), 1357-1357 (2019-02-06)
Tungsten Disulfide (WS2) is considered to be a promising Hydrogen Evolution Reaction (HER) catalyst to replace noble metals (such as Pt and Pd). However, progress in WS2 research has been impeded by the inertness of the in-plane atoms during HER.

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. Hello. Could you possibly provide me with the average particle size and a brief description of the particle shape? I am looking for small, homogeneous nano-particles. An SEM image would be greatly appreciated. Thank you.

    1 answer
    1. The particle size of this product is not determined, but is expected to be less than 2 mm. Unfortunately, an SEM image is currently not available.

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