所有图片(2)
About This Item
线性分子式:
MoCl5
CAS号:
分子量:
273.21
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23
化驗:
95%
形狀:
powder
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蒸汽壓力
1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)
品質等級
化驗
95%
形狀
powder
反應適用性
reagent type: catalyst
core: molybdenum
雜質
<0.5% insoluble matter
bp
268 °C (lit.)
mp
194 °C (lit.)
密度
2.928 g/mL at 25 °C (lit.)
應用
battery manufacturing
SMILES 字串
Cl[Mo](Cl)(Cl)(Cl)Cl
InChI
1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
InChI 密鑰
GICWIDZXWJGTCI-UHFFFAOYSA-I
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一般說明
氯化钼（V）是一种路易斯酸，被广泛用作许多有机反应的催化剂和试剂。它可以由钼金属的直接氯化或亚硫酰氯和 MoO3的加热回流制备。
應用
氯化钼（V）可用作以下反应的高效催化剂：
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体，用于化学选择性羰基烯化反应。
- 硝基苯和醇的缩合以及烯基锂试剂的C-C偶联。
- 苄基醇与磺胺和氨基甲酸酯的直接酰胺化反应。
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体，用于化学选择性羰基烯化反应。
訊號詞
Danger
危險聲明
危險分類
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
Kumar, S. Manickam, M.
Chemical Communications (Cambridge, England), 1615-1615 (1997)
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
Simon Trosien et al.
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular
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