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Merck
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642452

Sigma-Aldrich

五氯化钼

anhydrous, powder, 99.99% trace metals basis (excluding W)

别名:

Molybdenum pentachloride, Molybdenum(5+) chloride

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About This Item

线性分子式:
MoCl5
CAS号:
10241-05-1
分子量:
273.21
EC號碼:
233-575-3
MDL號碼:
MFCD00003467
分類程式碼代碼:
12352302
PubChem物質ID:
24883197
NACRES:
NA.23

等級

anhydrous

蒸汽壓力

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

化驗

99.99% trace metals basis (excluding W)

形狀

powder

雜質

≤150.0 ppm Trace Metal Analysis

bp

268 °C (lit.)

mp

194 °C (lit.)

密度

2.928 g/mL at 25 °C (lit.)

應用

battery manufacturing

SMILES 字串

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

InChI 密鑰

GICWIDZXWJGTCI-UHFFFAOYSA-I

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相关类别

一般說明

氯化钼(V) ，也称五氯化钼，是一种路易斯酸，具有高氧化电位。它被广泛用作有机合成和聚合物化学领域的催化剂。它也用作化学气相沉积的前体。

應用

氯化钼(V) 可用于:
  • 作为催化剂用于仲苄醇 的酰胺化。
  • 作为前体用于通过原子层沉积法制备MoS2薄膜 。
  • 作为丁二烯配位聚合的 主要催化剂。
  • 制备用于钠离子和 锂离子电池的优良负极材料。
  • 作为Li–O2电池的双功能氧化还原介体，用于克服高极化和低能量密度问题。

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

分析证书(COA)

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氧化钼(VI) 99.97% trace metals basis

Sigma-Aldrich

203815

氧化钼(VI)

氯化铌(V) ≥99.9% trace metals basis

Sigma-Aldrich

336602

氯化铌(V)

锡 powder, -100 mesh, 99.99% trace metals basis

Sigma-Aldrich

755702

锡

MoCl5 as a dual-function redox mediator for Li-O2 batteries
Xin-Gai Wang, et al.
Journal of Materials Chemistry, 7, 14239-14243 (2019)
Molybdenum(V) chloride-catalyzed amidation of secondary benzyl alcohols with sulfonamides and carbamates
Ch. Raji Reddy, et al.},
Tetrahedron Letters, 48, 7169-7172 (2007)
m-Cresol-substituted triethyl aluminum/MoCl5/TBP catalytic system for coordination polymerization of butadiene
Peipei Li, et al.
Iranian Polymer Journal, 27, 537-544 (2018)
Atomic layer deposition of a MoS2 film
Lee Kheng Tan, et al.},
Nanoscale, 6, 10584-10588 (2014)
Towards high-volumetric performance of Na/Li-ion batteries: A better anode material with molybdenum pentachloride--graphite intercalation compounds (MoCl 5--GICs
Zheng Li, et al.
Journal of Materials Chemistry, 8, 2430-2438 (2020)
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