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240761

Sigma-Aldrich

1-己烯

≥99%

别名:

1-n-Hexene

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50 ML
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100 ML
$60.10

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50 ML
$44.00
100 ML
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About This Item

线性分子式:
CH3(CH2)3CH=CH2
CAS号:
592-41-6
分子量:
84.16
Beilstein:
1209240
EC 号:
209-753-1
MDL编号:
MFCD00009505
UNSPSC代码:
12352100
PubChem化学物质编号:
24854435
NACRES:
NA.22

$44.00

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蒸汽密度

3 (vs air)

质量水平

100

蒸汽压

155 mmHg ( 21.1 °C)

方案

≥99%

表单

liquid

自燃温度

487 °F

折射率

n20/D 1.388 (lit.)

沸点

60-66 °C (lit.)

密度

0.678 g/mL at 25 °C (lit.)

官能团

allyl

SMILES字符串

CCCCC=C

InChI

1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3

InChI key

LIKMAJRDDDTEIG-UHFFFAOYSA-N

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相关类别

一般描述

1-己烯的聚合动力学已通过使用五锆胺双酚酸盐催化剂家族进行研究[1]。由一系列铪配合物催化的1-己烯的聚合反应已有研究[2]。

应用

  • 1-己烯在高分子量聚合物中的合成：使用Lewis酸催化剂从1-己烯和丙烯酸甲酯合成高分子量共聚物，展示了材料科学领域的先进应用，特别是在开发耐用和多功能高分子材料方面（Wan et al., 2024）。
  • 1-己烯在质子交换膜增强中的作用：利用1-己烯表征和增强功能多孔质子交换膜的物理化学性质，突出了它在提高燃料电池技术的能源效率和性能方面的关键作用（Ponomar et al., 2024）。

象形图

FlameHealth hazard
GHS02,GHS08

警示用语：

Danger

危险声明

H225,H304

危险分类

Asp. Tox. 1 - Flam. Liq. 2

补充剂危害

EUH066

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

-13.0 °F - closed cup

闪点(°C)

-25.0 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCK4596
SHBK4794
SHBJ3280
SHBH8693
SHBD7981V

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Takahiro Yasumoto et al.
Dalton transactions (Cambridge, England : 2003), 42(25), 9120-9128 (2012-12-14)
Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
Lingyan Gong et al.
Journal of colloid and interface science, 569, 219-228 (2020-03-01)
The current mechanism of surfactant enhanced oil recovery (EOR) mainly relies on forming middle-phase microemulsions to get ultra-low oil-water interfacial tension. However, residual oil can also be recovered using low concentration surfactant solutions without microemulsion formation, and the interaction between
Chia-Hsiu Chen et al.
Journal of the American Chemical Society, 137(21), 6965-6971 (2015-05-12)
The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
Yuichi Ito et al.
Implant dentistry, 24(4), 477-479 (2015-06-04)
The evaluation of bone quality at the site of the alveolar bone for a dental implant is very important. This study presents an easy technique for direct evaluation of alveolar bone quality using nondecalcified cryofilm frozen sections on human alveolar
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  1. How can I determine the shelf life / expiration / retest date of this product?

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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