237582

2-苯基亚磺酰基乙酸甲酯

98%

• 线性分子式: C₆H₅S(O)CH₂CO₂CH₃
• CAS号: 14090-83-6
• 分子量: 198.24
• Beilstein: 1953383
• EC 号: 237-936-6
• MDL编号: MFCD00002087
• UNSPSC代码: 12352100
• PubChem化学物质编号: 24854255
• NACRES: NA.22

属性

• 方案: 98%
• 表单: solid
• 沸点: 130-131 °C/0.5 mmHg (lit.)
• mp: 52-54 °C (lit.)
• SMILES字符串: COC(=O)CS(=O)c1ccccc1
• InChI: 1S/C9H10O3S/c1-12-9(10)7-13(11)8-5-3-2-4-6-8/h2-6H,7H2,1H3
• InChI key: JPPXZUDQIXZLIL-UHFFFAOYSA-N

说明

一般描述

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

应用

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

安全信息

• 储存分类代码: 13 - Non Combustible Solids
• WGK: WGK 3
• 闪点(°F): 235.4 °F - closed cup
• 闪点(°C): 113 °C - closed cup
• 个人防护装备: Eyeshields, Gloves, type N95 (US)