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Merck

563919

Sigma-Aldrich

氯化铝

anhydrous, powder, 99.999% trace metals basis

别名:

三氯化铝, 三氯铝, 氯化铝(III)

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About This Item

线性分子式:
AlCl3
CAS号:
分子量:
133.34
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
eCl@ss:
38120507
PubChem物質ID:
NACRES:
NA.23

等級

anhydrous

蒸汽壓力

1 mmHg ( 100 °C)

化驗

99.999% trace metals basis

形狀

powder

反應適用性

reagent type: catalyst
core: aluminum

雜質

≤15.0 ppm Trace Metal Analysis

mp

190 °C (lit.)

SMILES 字串

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI 密鑰

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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一般說明

Aluminum chloride is a strong Lewis acid and a major industrial catalyst. It is also used as a dopant/catalyst modifier to fabricate battery materials and solar cells.

應用

Aluminum chloride can be used:
  • To prepare cost-effective ionic liquid electrolyte for high performance aluminum ion battery.
  • To fabricate modified SnO2 triple layered photoanode for dye sensitized solar cells. This leads to suppression of electron recombination and five-fold enhancement of efficiency.
  • As a precursor to synthesize CsPbCl3 perovskite nanocrystals for bright white light-emitting diodes. It improves photoluminescence quantum yield.

特點和優勢

氢与其他金属卤化物的气相共还原作用可用于金属间的精细分离,可作为结构材料或化合物使用,具有重要热电、磁和抗氧化性能。 氮化铝可以由添加了AlCl3 的元素合成,以促进结晶。
  • High purity with trace metal analysis (=< 15 ppm) makes suitable for batteries.
  • High water solubility
  • Stable under battery operation conditions

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

安全危害

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


分析证书(COA)

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访问文档库

Low-temperature modification of mesoporous MCM-41 material with sublimated aluminum chloride in vacuum
Xu M, et al.
The Journal of Physical Chemistry B, 106(47), 12140-12143 (2002)
Lewis-acid catalyzed ene reactions
Snider BB
Accounts of Chemical Research, 13(11), 426-432 (1980)
Aluminium, Gallium, Indium and Thallium
Chemistry of elements, 216-267 (1997)
Reactions of Diazirines with Aluminum Chloride: Lewis Acid-Mediated Carbene Generation and Friedel- Crafts Reactions
Moss RA, et al.
Journal of the American Chemical Society, 122(40), 9878-9879 (2000)
Reaction of xylenes with tert.-butylchloride in presence of anhydrous aluminium chloride
Ismail M, et al.
The Journal of Physical Chemistry B, 106(47), 12140-12143 (2008)

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