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About This Item
线性分子式:
TlOC2H5
CAS号:
分子量:
249.44
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.22
推荐产品
形狀
liquid
品質等級
反應適用性
core: thallium
reagent type: catalyst
折射率
n20/D 1.676 (lit.)
密度
3.522 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
CCO[Tl]
InChI
1S/C2H5O.Tl/c1-2-3;/h2H2,1H3;/q-1;+1
InChI 密鑰
DZFYOYRNBGNPJW-UHFFFAOYSA-N
應用
用HCl还原各种官能团；羰基化合物的立体选择性烯丙基化；原位生成锡烯醇化物用于定向羟醛反应。
訊號詞
Danger
危險分類
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
235.4 °F - closed cup
閃點（°C）
113 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Yann Sarazin et al.
Journal of the American Chemical Society, 129(4), 881-894 (2007-01-25)
The reaction of thallium ethoxide with [H(OEt2)2][H2N{B(C6F5)3}2] in diethyl ether afforded [Tl(OEt2)3][H2N{B(C6F5)3}2] (2a), [Tl(OEt2)4][H2N{B(C6F5)3}2] (2b), or [Tl(OEt2)2][H2N{B(C6F5)3}2].CH2Cl2 (2c), depending on the reaction conditions. The dication in the hydrolysis product [Tl4(mu3-OH)2][H2N{B(C6F5)3}2]2.4CH2Cl2 consists of two bridging and two terminal Tl+ ions bound
Andrews, P. C.; Peatt, A. C.; Raston, C. L.
Tetrahedron Letters, 43, 7541-7541 (2002)
T Tsuchiya et al.
Journal of pharmacobio-dynamics, 12(8), 456-460 (1989-08-01)
The reduction of acute toxicity of paraquat dichloride (PQ) in mice was studied by several sodium sugar sulfates such as dextran sulfate (DS), cellulose sulfate (CS), chondroitin sulfate (CDS), sucrose sulfate (SS) and glucose sulfate (GS). When sugar sulfates (DS
Chan, T. H.; Li, C. J.; Wei, Z. Y.,
Journal of the Chemical Society. Chemical Communications, 505-505 (1990)
Michel J Kohl et al.
Steroids, 67(1), 71-75 (2001-12-01)
Conjugation of haptens through ether linkages avoids leakage problems in immunoassays, but this procedure is not easily applied to most steroids that bear low reacting hydroxyls. A new technique allowing the ether coupling of biologically active steroids with conjugating arms
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