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Merck

106399

Sigma-Aldrich

1-金刚烷甲酸

99%

别名:

Adamantane carboxylic acid

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25 G
$105.00
100 G
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About This Item

经验公式(希尔记法):
C11H16O2
CAS号:
分子量:
180.24
Beilstein:
1910637
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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质量水平

方案

99%

mp

172-174 °C (lit.)

官能团

carboxylic acid

SMILES字符串

OC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI

1S/C11H16O2/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2,(H,12,13)/t7-,8+,9-,11-

InChI key

JIMXXGFJRDUSRO-KJZNFTALSA-N

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应用

1-金刚烷甲酸可用于:
  • 在单分散、高结晶度的CoPt3纳米颗粒[1]和多孔铂纳米颗粒合成中用作稳定剂。[2]
  • 作为缩聚反应添加剂,生成共轭聚合物作为光电材料。[3]
  • 作为水介质中钯催化烯丙基取代反应的添加剂。[4]

生化/生理作用

1-金刚烷羧酸与环己烷多糖发生络合反应[5]。它是苯酯水解环七直链淀粉的抑制剂[6]

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of porous platinum nanoparticles.
Xiaowei Teng et al.
Small (Weinheim an der Bergstrasse, Germany), 2(2), 249-253 (2006-12-29)
Fang-Fei Zhu et al.
Food chemistry, 257, 382-387 (2018-04-07)
Amantadine (AMD), a banned antiviral veterinary drug, is still being abused. This study developed a novel enzyme linked immunosorbent assay for the colorimetric detection of AMD involving DNA hybridization reaction and non-crosslinking gold nanoparticles (AuNPs) aggregation. Accordingly, the Primer 1-AuNPs-anti-AMD
Ying-Ming Zhang et al.
Bioorganic & medicinal chemistry, 18(4), 1415-1420 (2010-02-05)
A novel beta-cyclodextrin derivative 1 bearing 8-hydroxyquinolino and triazole groups was synthesized in satisfactory yield by 'click chemistry'. With a good water solubility up to 0.03 mol/L, 1 exhibited an effective switch-on fluorescence response to Cd(2+) over other common metal
Nicolas Taulier et al.
The journal of physical chemistry. B, 112(31), 9546-9549 (2008-07-16)
We report temperature-dependent ultrasonic velocimetric and densimetric data on changes in volume, expansibility, and adiabatic compressibility associated with the binding of 1-adamantanecarboxylic acid (AD) to gamma-cyclodextrin (gamma-CD). We compare these results with our previous data on the binding of AD
D Rozema et al.
Biochemistry, 35(49), 15760-15771 (1996-12-10)
Conditions that promote renaturation of an unfolded protein also promote protein aggregation, in many cases, because these competing intramolecular and intermolecular processes are driven by similar networks of noncovalent interactions. The GroEL/GroES system and related biological chaperones facilitate the renaturation

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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