95447

Bis[tris(4-(1H,1H,2H,2H-perfluorodecyl)phenyl)phosphine]palladium(II) dichloride

technical, ≥80% (AAS)

• Synonim(y): Bis[tris(4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)phenyl)phosphine]palladium(II) dichloride
• Wzór empiryczny (zapis Hilla): C₉₆H₄₈Cl₂F₁₀₂P₂Pd
• Numer CAS: 326475-46-1
• Masa cząsteczkowa: 3378.52
• NACRES: NA.21
• PubChem Substance ID: 329770462
• UNSPSC Code: 12161600
• MDL number: MFCD03453279

Właściwości

• grade: technical
• Quality Level: 100
• assay: ≥80% (AAS)
• form: powder
• reaction suitability: reagent type: catalyst; core: palladium
• mp: 175-180 °C
• SMILES string: Cl[Pd]Cl.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc1ccc(cc1)P(c2ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc2)c3ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc3.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc4ccc(cc4)P(c5ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc5)c6ccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)cc6
• InChI: 1S/2C48H24F51P.2ClH.Pd/c2*49-25(50,28(55,56)31(61,62)34(67,68)37(73,74)40(79,80)43(85,86)46(91,92)93)16-13-19-1-7-22(8-2-19)100(23-9-3-20(4-10-23)14-17-26(51,52)29(57,58)32(63,64)35(69,70)38(75,76)41(81,82)44(87,88)47(94,95)96)24-11-5-21(6-12-24)15-18-27(53,54)30(59,60)33(65,66)36(71,72)39(77,78)42(83,84)45(89,90)48(97,98)99;;;/h2*1-12H,13-18H2;2*1H;/q;;;;+2/p-2
• InChI key: KONKDVXTNQEYIF-UHFFFAOYSA-L

Opis

General description

contains up to 20% Tri(4-(1H,1H,2H,2H-perfluorodecyl)phenyl)phosphine oxide

Application

Catalyst for Stille and Suzuki couplings in Fluorous Biphase Systems (FBS)

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Perfluoro-tagged Pd complexes as catalysts for Stille couplings in a fluorous biphasic system,[1] palladium-catalyzed Suzuki couplings.

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Informacja o środkach bezpieczeństwa

• pictograms: GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H302 + H332,H318,H351,H360D,H362,H372
• pcodes: P260 - P263 - P280 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1
• target_organs: Liver
• Klasa składowania: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)