74332

Diazinon-(diethyl-d₁₀)

PESTANAL^®, analytical standard

• Wzór empiryczny (zapis Hilla): C₁₂D₁₀H₁₁N₂O₃PS
• Numer CAS: 100155-47-3
• Masa cząsteczkowa: 314.41
• NACRES: NA.24
• PubChem Substance ID: 329765626
• UNSPSC Code: 77101502
• MDL number: MFCD00144095

Właściwości

• grade: analytical standard
• Quality Segment: 100
• isotopic purity: ≥95 atom % D
• product line: PESTANAL^®
• assay: ≥97.5% (GC)
• shelf life: limited shelf life, expiry date on the label
• refractive index: n20/D 1.4978 (lit.)
• bp: 83-84 °C/0.002 mmHg (lit.)
• application(s): agriculture; environmental
• format: neat
• mass shift: M+10
• storage temp.: 2-8°C
• SMILES string: [2H]C([2H])([2H])C([2H])([2H])OP(=S)(Oc1cc(C)nc(n1)C(C)C)OC([2H])([2H])C([2H])([2H])[2H]
• InChI: 1S/C12H21N2O3PS/c1-6-15-18(19,16-7-2)17-11-8-10(5)13-12(14-11)9(3)4/h8-9H,6-7H2,1-5H3/i1D3,2D3,6D2,7D2
• InChI key: FHIVAFMUCKRCQO-HXOHQZFQSA-N

Opis

General description

Diazinon-(diethyl-d₁₀) is an isotope labeled analog of the organophosphate pesticide diazinon, wherein the diethoxy protons are replaced by deuterium.

Application

Diazinon-(diethyl-d₁₀) may be used as an internal standard for the determination of diazinon in soybeans and Daphnia magna by various chromatography techniques.

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis, potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Informacja o środkach bezpieczeństwa

• pictograms: GHS06,GHS09
• signalword: Danger
• hcodes: H301,H410
• pcodes: P264 - P273 - P301 + P310 - P391 - P405 - P501
• Hazard Classifications: Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Klasa składowania: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk: WGK 3
• flash_point_f: 235.0 °F - closed cup
• flash_point_c: 112.8 °C - closed cup