762830

JackiePhos Pd G3

95%, solid

• Synonim(y): JackiePhos-Pd-G3, [(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
• Wzór empiryczny (zapis Hilla): C₅₂H₅₀F₁₂NO₅PPdS
• Numer CAS: 2102544-35-2
• Masa cząsteczkowa: 1166.40
• UNSPSC Code: 12161600
• PubChem Substance ID: 329767007
• NACRES: NA.22
• MDL number: MFCD22572672

Właściwości

• Nazwa produktu: JackiePhos Pd G3, 95%
• Quality Segment: 100
• product line: Buchwald precatalyst Generation 3
• assay: 95%
• form: solid
• feature: generation 3
• reaction suitability: core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst; reaction type: Cross Couplings
• mp: 195-197 °C (decomposition)
• functional group: phosphine
• SMILES string: CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.COc3ccc(OC)c(c3P(c4cc(cc(c4)C(F)(F)F)C(F)(F)F)c5cc(cc(c5)C(F)(F)F)C(F)(F)F)-c6c(cc(cc6C(C)C)C(C)C)C(C)C
• InChI: 1S/C39H37F12O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-11-29(20(3)4)33(30(12-22)21(5)6)34-31(52-7)9-10-32(53-8)35(34)54(27-15-23(36(40,41)42)13-24(16-27)37(43,44)45)28-17-25(38(46,47)48)14-26(18-28)39(49,50)51;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-21H,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
• InChI key: LLXGRQGGARSAOC-UHFFFAOYSA-M

Opis

Application

JackiePhos Pd G3 can be used as a palladium precatalyst in Stille cross-coupling reaction between organostannane and ary halides.

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable