708682

RuCl[(R,R)-TsDPEN](mesitylene)

90%

• Synonim(y): [N-[(1R,2R)-2-(Amino-κN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium
• Wzór empiryczny (zapis Hilla): C₃₀H₃₃ClN₂O₂RuS
• Numer CAS: 174813-82-2
• Masa cząsteczkowa: 622.18
• NACRES: NA.22
• PubChem Substance ID: 329762817
• UNSPSC Code: 12352116
• MDL number: MFCD12545951

Właściwości

• Quality Segment: 100
• assay: 90%
• form: solid
• reaction suitability: reagent type: catalyst; core: ruthenium; reaction type: Noyori Asymmetric Hydrogenation
• mp: 241-249 °C
• functional group: amine, phenyl
• storage temp.: 2-8°C
• SMILES string: Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
• InChI key: XBNBOGZUDCYNOJ-AGEKDOICSA-M

Opis

Application

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

• (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
• Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Legal Information

Sold in collaboration with Takasago for research purposes only. WO9720789

Ta strona może zawierać tekst przetłumaczony maszynowo.

Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)