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Merck

650501

Sigma-Aldrich

丙酮

Acetone

HPLC Plus, for HPLC, GC, and residue analysis, ≥99.9%

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About This Item

线性分子式:
CH3COCH3
CAS号:
分子量:
58.08
Beilstein:
635680
EC 号:
MDL编号:
UNSPSC代码:
12190000
eCl@ss:
39021201
PubChem化学物质编号:
NACRES:
NA.02
价格与库存信息目前不能提供

等级

HPLC Plus
HPLC grade
for residue analysis

Agency

suitable for EPA 1613
suitable for EPA 1633

蒸汽密度

2 (vs air)

蒸汽压

184 mmHg ( 20 °C)

方案

≥99.9%

表单

liquid

expl. lim.

13.2 %

技术

HPLC: suitable
gas chromatography (GC): suitable

杂质

≤0.5% water
≤1.0 ppb Fluorescence (quinine) at 365 nm

蒸发残留物

≤0.0003%

卤代烷残留物

<10 ng/L (as heptachlor epoxide)

折射率

n20/D 1.359 (lit.)

pH值(酸碱度)

5-6 (20 °C, 395 g/L)

沸点

56 °C/760 mmHg (lit.)

mp

−94 °C (lit.)

溶解性

water: miscible

密度

0.791 g/mL at 25 °C (lit.)

λ

H2O reference

紫外吸收

λ: 330 nm Amax: 1.0
λ: 340 nm Amax: 0.06
λ: 350 nm Amax: 0.01
λ: 375-400 nm Amax: 0.005

适用性

suitable for residue analysis

应用

PFAS testing
food and beverages

包装形式

neat

SMILES字符串

CC(C)=O

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

InChI key

CSCPPACGZOOCGX-UHFFFAOYSA-N

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相关类别

一般描述

丙酮是一种酮。据报道,在700℃或650℃下煅烧的TiO2 (P25) 与稀土氧化物(La2O3 or Y2O3)的混合物可有效地光催化丙酮的氧化。[1]已有研究描述了在碱(Li,Na,K和Cs)或碱土(Ca,Sr和Ba)金属离子促进的MgO催化下,丙酮在气相中的醛醇缩合反应。[2]在使用Mg-Al层状双氢氧化物(LDH)作为催化剂并使用Cl- 和/或CO32- 作为补偿阴离子时,丙酮可通过醇醛缩合反应,生成二丙酮醇和甲基异丁烯甲酮。[3]已有研究描述了在二肽(催化剂)存在下,丙酮与各种靛红的对映选择性醇醛缩合。[4]

应用

丙酮可用于以下研究:
  • 生物样品(血液)中葡萄糖代谢的NMR光谱评估。[5]
  • 制备13wt%无定形聚乳酸(PLA)溶液,这是制备静电纺聚乳酸膜所必需的。[6]
  • 作为在磺化氧化石墨烯-Pd/堇青石催化剂存在下合成甲基异丁基酮(MIBK)的前体。[7]
  • 使用超临界流体(SCF)技术合成(4-羟甲基-2,2-二甲基-1,3-二氧环戊烷),一种甘油缩酮。[8]
可用于合成以下丙酮腙:
  • 1-异亚丙基-2-甲基肼[9]
  • 1-异亚丙基-2-羟乙基肼[9]
  • 1-异亚丙基-2-甲酰肼[9]
丙酮的发光强度取决于溶液组分。丙酮吸收UV光,导致丙酮光分解和放射性产物。
适用于HPLC、分光光度法、环境测试

包装

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!

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象形图

FlameExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

靶器官

Central nervous system

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

-6.2 °F

闪点(°C)

-21.2 °C


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Ketalization of glycerol to solketal in supercritical acetone.
Royon D, et al.
Journal of Supercritical Fluids, 58(1), 88-92 (2011)
Synthesis and characterization of acetone hydrazones.
Miro SC and Delalu H.
Zeitschrift fur Anorganische und Allgemeine Chemie, 638(1), 57-63 (2012)
Sulfonated graphene oxide supported Pd bifunctional catalyst for one-pot synthesis of methyl isobutyl ketone from acetone with high conversion and selectivity.
Liu M, et al.
J. Mol. Catal. A: Chem., 408, 85-90 (2015)
Saskia Kley et al.
American journal of physiology. Regulatory, integrative and comparative physiology, 296(4), R936-R943 (2009-02-06)
Obesity is a risk factor for type 2 diabetes in cats. The risk of developing diabetes is severalfold greater for male cats than for females, even after having been neutered early in life. The purpose of this study was to
Development of eco-efficient micro-porous membranes via electrospinning and annealing of poly (lactic acid).
Li L, et al.
Journal of Membrane Science, 436, 57-67 (2013)

商品

Compare PAH determination in olive oil: traditional GB 5009.265-2021 method vs. faster, simpler SPE with Supelclean EZ-POP NP; both meet criteria.

Compare PAH determination in olive oil: traditional GB 5009.265-2021 method vs. faster, simpler SPE with Supelclean EZ-POP NP; both meet criteria.

Compare PAH determination in olive oil: traditional GB 5009.265-2021 method vs. faster, simpler SPE with Supelclean EZ-POP NP; both meet criteria.

Compare PAH determination in olive oil: traditional GB 5009.265-2021 method vs. faster, simpler SPE with Supelclean EZ-POP NP; both meet criteria.

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This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. quel est origine de l'acétone HPLC? synthèse, biosourcing?

    1 answer
    1. This product is typically manufactured as synthetic organic, however, may vary lot to lot. This information can be found on the lot specific Certificate of Origin. Please navigate to the ‘DOCUMENTATION’ section of the Product Detail Page to access a Certificate under the ‘Certificate of Origin’ tab:
      https://www.sigmaaldrich.com/product/sigald/650501#product-documentation

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