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Merck

207942

Sigma-Aldrich

肼 一水合物

N2H4 64-65 %, reagent grade, ≥97%

别名:

水合肼

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About This Item

线性分子式:
NH2NH2 · H2O
CAS号:
分子量:
50.06
Beilstein:
878137
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
价格与库存信息目前不能提供

等级

reagent grade

质量水平

蒸汽密度

>1 (vs air)

蒸汽压

5 mmHg ( 25 °C)

方案

≥97%

表单

liquid

组成

N2H4, 64-65%

expl. lim.

99.99 %

折射率

n20/D 1.428 (lit.)

pH值(酸碱度)

10.6-10.7 (10 g/L)

沸点

120.1 °C (lit.)

mp

−51.7 °C (lit.)

密度

1.032 g/mL at 25 °C (lit.)

SMILES字符串

O.NN

InChI

1S/H4N2.H2O/c1-2;/h1-2H2;1H2

InChI key

IKDUDTNKRLTJSI-UHFFFAOYSA-N

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一般描述

一水合肼晶体呈三斜晶系和空间基P3121。[1]

应用

一水合肼已用于合成2-(6-乙胺-3-乙阈值-2,7-二甲基- 3H-黄酮-9-基)苯甲酸肼[2]和盐酸乙烯基苄胺。[3]在存在Ni-Pt合金纳米颗粒和介孔CeO2载体组成的负载型双金属催化剂的情况下,它也可以作为氢的来源进行分解。[4]
一水合肼可作为还原硝基芳烃的还原剂:
  • 过氧化氢官能化碳纳米管中存在硝基芳烃的情况下。[5]
  • 4-碘-3-硝基茴香醚生成2-碘-5-甲氧基苯胺。[6]
  • 氧化石墨烯(GO)形成石墨烯。[7]

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警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

100.4 °F - closed cup - (anhydrous substance)

闪点(°C)

38 °C - closed cup - (anhydrous substance)

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Convergent synthesis of the quinolone substructure of BILN 2061 via carbonylative Sonogashira coupling/cyclization.
Haddad N, et al.
The Journal of Organic Chemistry, 71(13), 5031-5034 (2006)
Carbon nanotubes oxidized by a green method as efficient metal-free catalysts for nitroarene reduction.
Wu S, et al.
Physical Chemistry Chemical Physics, 17(3), 1567-1571 (2015)
Yuan-Yuan Jiang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(43), 15439-15445 (2015-10-17)
The development of active, selective, and robust catalysts is a key issue in promoting the practical application of hydrazine monohydrate (N2 H4 ⋅H2 O) as a viable hydrogen carrier. Herein, the synthesis of a supported Ni-Pt bimetallic nanocatalyst on mesoporous
High performance supercapacitor for efficient energy storage under extreme environmental temperatures.
Vellacheri R, et al.
Nano Energy, 8, 231-237 (2014)
The crystal structure of hydrazine monohydrate.
Liminga R and Olovsson I.
Acta Crystallographica, 17(12), 1523-1528 (1964)

Questions

1–4 of 4 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hi, is this a salt or solution?

    1 answer
    1. This product is a monohydrate and is a liquid at room temperature with a density of 1.032 g/mL. The material is 64 - 65% Hydrazine with the remainder being water. This material is not a salt form.

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  4. Is there a shelf life for this product and if so how long will it last?

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

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