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Merck

86578

Sigma-Aldrich

原硅酸四乙酯

≥99.0% (GC)

别名:

TEOS, 四乙氧基硅烷, 四乙氧基硅烷(IV), 四氧化硅, 硅酸四乙酯, 原硅酸四乙酯

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About This Item

线性分子式:
Si(OC2H5)4
CAS号:
分子量:
208.33
Beilstein:
1422225
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
价格与库存信息目前不能提供

蒸汽密度

7.2 (vs air)

质量水平

蒸汽压

<1 mmHg ( 20 °C)

方案

≥99.0% (GC)

表单

liquid

技术

GC/GC: suitable

折射率

n20/D 1.382 (lit.)
n20/D 1.383

沸点

168 °C (lit.)

密度

0.933 g/mL at 20 °C (lit.)

SMILES字符串

CCO[Si](OCC)(OCC)OCC

InChI

1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3

InChI key

BOTDANWDWHJENH-UHFFFAOYSA-N

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一般描述

原硅酸四乙酯(TEOS)是一种无机材料,可用作二氧化硅源,用于合成各种二氧化硅基材料,如二氧化硅[1]、碳氧化硅[2]、硅烷醇[3]、硅氧烷聚合物[4]和有机硅薄膜[5],适于各种应用。它还可用于混合膜合成及气凝胶生产。[6]其他应用包括地毯和其他物体的涂料。[7]

应用

原硅酸四乙酯(TEOS)可用于:
  • 用作二氢嘧啶酮合成试剂,结合与氯化铁使用。[8]
  • 用作制作湿敏材料聚(2-丙烯酰胺基-2-甲基丙烷磺酸盐)(poly-AMPS)的改性剂。[9]
  • 用作通过铜催化、无配体Ullmann反应合成三芳基胺和二芳基醚的介质。[10]
  • 用作二氧化硅干凝胶制备的前体,可用于药物载体。[11]
  • 用作Stober法球状体二氧化硅颗粒合成的前体。[12]

将与十二胺相互作用形成 H+-麦烃硅钠石的插层化合物,并用于混合金属生物活性玻璃的研究。
常用作制备干凝胶的前体

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

113.0 °F - closed cup

闪点(°C)

45 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Silica xerogels as pharmaceutical drug carriers
Quintanar-Guerrero D, et al.
Expert Opinion on Drug Delivery, 5(6), 485-498 (2009)
Ullmann reaction in tetraethyl orthosilicate: a novel synthesis of triarylamines and diaryl ethers
Zhao Y, et al.
Chemical Communications (Cambridge, England), 30(449), 3186-3188 (2007)
Preparation of spherical silica particles by Stober process with high concentration of tetra-ethyl-orthosilicate
Wang XD, et al.
Journal of Colloid and Interface Science, 1(341), 23-29 (2010)
Preparation of silicon oxycarbide glass fibers from organically modified silicates
Hu, Yi
Journal of materials science & technology, 35(12), 3155-3159 (2000)
A spectroscopic study of an anhydrous tetraethyl orthosilicate-boric acid-ethanol system
Zha Congji, et al.
Journal of Sol-Gel Science and Technology, 13(1-3), 103-107 (1998)

Questions

1–10 of 12 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the thermal conductivity of TEOS?

    1 answer
    1. Unfortunately, the thermal conductivity of this product is not determined.

      Helpful?

  4. What is the electrical conductivity or resistivity of TEOS

    1 answer
    1. This product is not tested for electrical conductivity. The compound is not expected to be a conductive material. The presence of TEOS in various coatings may impact the conductivity or resistivity of a given target compound, such as a metallic nanoparticle. See the links below to review articles that may be of interest:
      https://www.researchgate.net/figure/Effect-of-the-addition-of-TEOS-on-a-density-b-resistivity-c-residual-magnetic_fig5_371096514
      https://link.springer.com/article/10.1007/s12633-019-00180-y

      Helpful?

  5. According to the theise, TEOS was used in units of g. Do you sell powder or solid TEOS?

    1 answer
    1. Tetraethyl orthosilicate is only available in the liquid state. The melting point of the pure compound is -82.5 °C. The density of this material is 0.933 g/mL.
      See the link below to review the PubChem profile.
      https://pubchem.ncbi.nlm.nih.gov/compound/Tetraethyl-orthosilicate#section=Melting-Point

      Helpful?

  6. What type of applications can Product No. 86578, Tetraethyl orthosilicate (TEOS), be used in?

    1 answer
    1. TEOS can be used to synthesize sol-gels or aerogels.

      Helpful?

  7. How do you create a sol-gel with Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. TEOS can be polymerized with water; the polymerization is based on the hydrolysis or the Si-O-Et groups through forming networks linked by Si-O-Si groups.

      Helpful?

  8. How does the storage temperature relate to shipping conditions?

    1 answer
    1. The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment.

      Helpful?

  9. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  10. What are the applications of sol-gels formed from Tetraethyl orthosilicate (TEOS), Product No. 86578?

    1 answer
    1. One of the most improtant application of the sol-gel process is the snythesis of zeolites. Other applications are optical ceramic materials or functionalized biosensors.

      Helpful?

1–10 of 12 Questions  

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