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Merck

701211

Sigma-Aldrich

乙酰丙酮酰双(亚乙基)化铑(I)

95%

别名:

Bis(η2-ethene)(2,4-pentanedionato-κOO′)-rhodium, Bis(ethylene)rhodium(I) acetylacetonate, 乙酰丙酮二(乙烯)铑, 乙酰丙酮二乙烯铑配合物, 二(乙烯)乙酰丙酮铑

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About This Item

经验公式(希尔记法):
C9H15O2Rh
CAS号:
分子量:
258.12
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

化驗

95%

形狀

solid

反應適用性

core: rhodium
reagent type: catalyst

mp

141-142 °C

儲存溫度

2-8°C

SMILES 字串

C=C.C=C.CC(=O)\C=C(\C)O[Rh]

InChI

1S/C5H8O2.2C2H4.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;2*1-2H2;/q;;;+1/p-1/b4-3-;;;

InChI 密鑰

FLRBEQQDEGBCJS-FGSKAQBVSA-M

一般說明

Acetylacetonatobis(ethylene)rhodium(I) is a coordination compound commonly used as a precursor to synthesize mononuclear rhodium complexes. In addition, it is also used as a catalyst in asymmetric arylation reactions.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Chiral bicyclic bridgehead phosphoramidite (briphos) ligands for asymmetric rhodium-catalyzed 1, 2-and 1, 4-addition
Lee A, et al.
The Journal of Organic Chemistry, 81(9) , 3520-3527 (2016)
Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane
Hao X, et al.
Catalysis Science & Technology, 1(1), 62-64 (2011)
Rhodium complex with ethylene ligands supported on highly dehydroxylated MgO: synthesis, characterization, and reactivity
Bhirud VA, et al.
Langmuir, 22(1), 490-496 (2006)

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