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684031

Sigma-Aldrich

(1S, 2S)-1,2-双(4-硝基苯基)乙二胺二盐酸盐

97%

别名:

(1S, 2S)-1,2-Bis(4-nitrophenyl)-1,2-ethanediamine dihydrochloride

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About This Item

经验公式（希尔记法）:
C14H14N4O4 · 2HCl
CAS号:
1052707-07-9
分子量:
375.21
MDL號碼:
MFCD09836223
分類程式碼代碼:
12352116
PubChem物質ID:
329760889
NACRES:
NA.22
价格与库存信息目前不能提供

品質等級

100

化驗

97%

形狀

powder

光學活性

[α]22/D -84.0°, c = 1 in H2O

mp

202-207 °C

官能基

amine
nitro

SMILES 字串

Cl.Cl.N[C@H]([C@@H](N)c1ccc(cc1)[N+]([O-])=O)c2ccc(cc2)[N+]([O-])=O

InChI

1S/C14H14N4O4.2ClH/c15-13(9-1-5-11(6-2-9)17(19)20)14(16)10-3-7-12(8-4-10)18(21)22;;/h1-8,13-14H,15-16H2;2*1H/t13-,14-;;/m0../s1

InChI 密鑰

PDPYGNJVCKPVGM-AXEKQOJOSA-N

相关类别

應用

(1S, 2S)-1,2-Bis(4-nitrophenyl)ethylenediamine dihydrochloride can be used to prepare a fluorous Fe-salen complex, which is used as a catalyst in the asymmetric epoxidation of C-C double bonds.[1]

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H302

危險分類

Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCM7939
MKBW8521V
66997MJ
12729EH

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Unprecedented Asymmetric Epoxidation of Isolated Carbon-Carbon Double Bonds by a Chiral Fluorous Fe (III) Salen Complex: Exploiting Fluorophilic Effect for Catalyst Design
Kobayashi Y, et al.
European Journal of Organic Chemistry, 2019(13), 2401-2408 (2019)

商品

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

相关内容

Chin Group – Professor Product Portal

The Chin group is interested in computational and experimental approaches to understanding stereoselective recognition and catalysis. Their studies in weak forces (H-bonding, electronic and steric effects) has led to a highly efficient method for making limitless varieties of chiral vicinal diamines from the 'mother diamine' that are useful for developing stereoselective organocatalysts or transition metal-based catalysts as well as for developing drugs (Acc Chem Res (2012) p1345). The 'mother diamine' is also useful for making binol, monophos and binap analogs. The Chin group is also interested in using reversible covalent bonds for stereoselective recognition and L to D conversion of natural and non-natural amino acids (EJOC (2012) p229).

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