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673293

Sigma-Aldrich

五甲基环戊二烯基双(三苯基膦)氯化钌(II)

别名:

Cp*RuCl(PPh3)2, 氯(五甲基环戊二烯基)双(三苯基膦)合钌(II)

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About This Item

线性分子式:
[(C10H15)Ru(P((C6H5)3))2Cl]
CAS号:
92361-49-4
分子量:
796.32
MDL编号:
MFCD09038426
UNSPSC代码:
12161600
PubChem化学物质编号:
24885155
NACRES:
NA.22
价格与库存信息目前不能提供

表单

solid

反应适用性

core: ruthenium
reagent type: catalyst
reaction type: click chemistry

mp

128 °C (D)

储存温度

2-8°C

SMILES字符串

Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

InChI

1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1

InChI key

KLXKSZDVKAWYRT-UHFFFAOYSA-M

相关类别

应用

叠氮化物与乙炔环加成反应的催化剂，专一性生成 1,5-二取代三唑，相比之下，常见的铜催化则具有 1,4-区域选择性。钌催化还使得可在此类"点击环加成反应"中使用内炔。[1]
活性自由基聚合反应的多功能催化剂[2]

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX3602
MKCV8801
MKCR2038
MKCS6094
MKCN4190

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Metal-catalyzed living radical polymerization.
M Kamigaito et al.
Chemical reviews, 101(12), 3689-3746 (2001-12-13)
Li Zhang et al.
Journal of the American Chemical Society, 127(46), 15998-15999 (2005-11-17)
Cp*RuCl(PPh3)2 is an effective catalyst for the regioselective "fusion" of organic azides and terminal alkynes, producing 1,5-disubstituted 1,2,3-triazoles. Internal alkynes also participate in this catalysis, resulting in fully substituted 1,2,3-triazoles.

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Click chemistry is an approach to the synthesis of drug-like molecules that can accelerate the drug discovery process by using a few practical and reliable reactions.

Introduction to Click Chemistry

Click chemistry is an approach to the synthesis of drug-like molecules that can accelerate the drug discovery process by using a few practical and reliable reactions.

Introduction to Click Chemistry

Click chemistry is an approach to the synthesis of drug-like molecules that can accelerate the drug discovery process by using a few practical and reliable reactions.

Introduction to Click Chemistry

Click chemistry is an approach to the synthesis of drug-like molecules that can accelerate the drug discovery process by using a few practical and reliable reactions.

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