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Merck

562629

Sigma-Aldrich

全氟-1-丁磺酸

97%

别名:

1,1,2,2,3,3,4,4,4-九氟-1-丁烷磺酸, 1-全氟丁烷磺酸, 九氟-1-丁烷磺酸, 九氟丁烷-1-磺酸, 九氟丁烷磺酸, 全氟丁烷磺酸, 正九氟丁烷磺酸

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About This Item

线性分子式:
CF3(CF2)3SO3H
CAS号:
分子量:
300.10
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
价格与库存信息目前不能提供

品質等級

化驗

97%

折射率

n20/D 1.3230 (lit.)

bp

112-114 °C/14 mmHg (lit.)

密度

1.811 g/mL at 25 °C (lit.)

官能基

fluoro
sulfonic acid

儲存溫度

2-8°C

SMILES 字串

OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C4HF9O3S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h(H,14,15,16)

InChI 密鑰

JGTNAGYHADQMCM-UHFFFAOYSA-N

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一般說明

九氟丁烷-1-磺酸是一种无色液体,可以被认为是一种超强酸 ,它可以通过 1-碘氟丁烷与连二亚硫酸钠在碳酸氢钠的乙腈/水溶液中反应合成。 [1]

應用

九氟丁烷-1-磺酸可作为催化剂用于合成 6-氯-6 H -二苯甲酮 [ c,e ] \ [1,2] 氧磷啉 [2] N -苄基吡啶-2-胺 [3]

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

350.6 °F - Pensky-Martens closed cup

閃點(°C)

177 °C - Pensky-Martens closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Slide 1 of 3

1 of 3

Black D
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 15 (2014)
Karilyn E Sant et al.
Toxicological sciences : an official journal of the Society of Toxicology, 167(1), 258-268 (2018-09-22)
Following the phase-out of highly persistent perfluorosulfonates in the United States from non-stick and stain-resistant products in the early 2000s, perfluorobutanesulfonic acid (PFBS) has replaced these compounds as a primary surfactant. Measurements of PFBS in environmental and human samples have
Lizhu Tang et al.
Chemosphere, 256, 127169-127169 (2020-05-29)
Parental exposure to perfluorobutane sulfonate (PFBS), an aquatic pollutant of emerging concern, is previously found to impair the embryonic development of offspring. However, the impairing mechanisms remain to clarify. In the present study, adult zebrafish were exposed to 0, 10
"A general method for the preparation of perfluoroalkanesulfonyl chlorides"
Scott.H.J P, et al.
Journal of Fluorine Chemistry, 126(8), 1196-1201 (2005)
Weipeng Qi et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 120, 340-345 (2018-07-22)
Perfluorobutanesulfonic acid (PFBS) is used as the replacement of perfluorooctanesulfonic acid (PFOS) since 2000 because of the concern on PFOS' persistence in the environment and the bioaccumulation in animals. Accumulating evidence has shown the correlation between the exposure to perfluorinated

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. 1. 이 제품은 액체로 되어있습니다. 표준원액을 만들어야 하는데 피펫으로 끌어올렸을때 하얗게 굳습니다. 굳기전에 재빠르게 무게를 재서 표준원액을 조제하면 농도가 잘 맞지 않습니다. 어떻게 조제하는 것이 정확할까요? 2. 뚜껑을 열었을 때 연기가 나오는데 어떤 현상이 있는건가요 조심해야하나요? 2. 메탄올에 녹이는 것이 좋을까요?

    1 answer
    1. This product is a liquid at room temperature and will only become a solid at -21°C or colder. It is strongly recommended to review the Safety Data Sheet prior to working with this chemical. It is important to handle this chemical under an inert gas atmosphere, as it reacts violently with water and moisture in the air, likely causing the issues described. Additionally, it should be stored under inert gas.

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