254142

氯化铋 (III)

99.99% trace metals basis

• 别名: 三氯化铋, 三氯铋
• 经验公式（希尔记法）: BiCl₃
• CAS号: 7787-60-2
• 分子量: 315.34
• EC號碼: 232-123-2
• MDL號碼: MFCD00003461
• 分類程式碼代碼: 12352302
• PubChem物質ID: 24855360
• NACRES: NA.23

属性

• 化驗: 99.99% trace metals basis
• 形狀: solid
• 反應適用性: reagent type: catalyst; core: bismuth
• 雜質: ≤150.0 ppm Trace Metal Analysis
• bp: 447 °C (lit.)
• mp: 230-232 °C (lit.)
• SMILES 字串: Cl[Bi](Cl)Cl
• InChI: 1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
• InChI 密鑰: JHXKRIRFYBPWGE-UHFFFAOYSA-K

说明

一般說明

Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi³⁺ ions used in various organic transformations and synthesis of bismuth nanomaterials.

應用

Bismuth(III) chloride can be used:

• As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance.
• As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs₂AgBiBr₆ and Cs₂AgBiCl₆, eco-friendly alternative to the lead halide perovskites.
• To form a protective layer on anode materials.

It can also be used as an efficient catalyst for green synthesis of:

• Chalcones by Claisen–Schmidt reaction under solvent-free conditions.
• One-pot three-component synthesis of Propargylamines.
• Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters.

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319
• 防範說明: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 2
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves