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Merck

222380

Sigma-Aldrich

氯化烯丙基钯(II)二聚体

greener alternative

98%

别名:

双((η3-烯丙基)(氯)钯), 二-ο-烯丙基二-μ-氯二钯, \ [氯化钯(C3H5)] 2

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About This Item

经验公式(希尔记法):
C6H10Cl2Pd2
CAS号:
分子量:
365.89
Beilstein:
4124623
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
价格与库存信息目前不能提供

质量水平

方案

98%

表单

solid

反应适用性

core: palladium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

环保替代产品分类

储存温度

2-8°C

SMILES字符串

Cl[Pd]CC=C.Cl[Pd]CC=C

InChI

1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2

InChI key

TWKVUTXHANJYGH-UHFFFAOYSA-L

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一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。 点击此处以获取更多信息。
氯化烯丙基钯二聚体被用作Heck反应的催化剂。它还作为催化剂参与炔醛与烯丙基氯和烯丙基丁基锡烷的串联亲核烯丙基化-烷氧基烯丙基化反应。[1]

应用

烯丙基钯(II)氯化物二聚体已用于以下研究:
  • 微波辅助Heck芳基化用阳离子钯催化剂的合成。[2]
  • N-杂环卡宾-钯-η3-烯丙基氯络合物的合成:它是芳基溴化物和活化芳基氯化物Suzuki-Miyaura交叉偶联的有效催化剂。[3]
  • 1,4-二烯丙基-1,2-二氢异喹啉的合成。[4]
  • 作为TPGS-750-M更绿色Buchwald-Hartwig耦合的催化剂

朝着通过E因子而量化的绿色过渡金属催化过程前进

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Suzuki cross-couplings of alkyl tosylates that possess beta hydrogen atoms: synthetic and mechanistic studies.
Matthew R Netherton et al.
Angewandte Chemie (International ed. in English), 41(20), 3910-3912 (2002-10-19)
Efficient Heck vinylation of aryl halides catalyzed by a new air-stable palladium-tetraphosphine complex.
M Feuerstein et al.
The Journal of organic chemistry, 66(17), 5923-5925 (2001-08-21)
Tandem nucleophilic allylation-alkoxyallylation of alkynylaldehydes via amphiphilic bis-p-allylpalladium complexes.
Nakamura H, et al.
Tetrahedron Letters, 43(42), 7631-7633 (2002)
An N-heterocyclic carbene-palladium-η3-allyl chloride complex for the Suzuki-Miyaura coupling of aryl halides.
Broekemier NW, et al.
European Journal of Chemistry, 5(1), 162-166 (2014)
Radetich, B.; RajanBabu, T. V.
Journal of the American Chemical Society, 120, 8007-8007 (1998)

商品

A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.

A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.

A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.

A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.

实验方案

TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.

TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.

TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.

TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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